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离子液体在锂、镍和钴萃取中的评估综述——传统方法

A review on assessment of ionic liquids in extraction of lithium, nickel, and cobalt conventional methods.

作者信息

Meshram Pratima, Agarwal Nikita

机构信息

CSIR-National Metallurgical Laboratory Jamshedpur 831007 India

Academy of Scientific and Innovative Research (AcSIR-NML) Jamshedpur India.

出版信息

RSC Adv. 2025 Mar 18;15(11):8321-8334. doi: 10.1039/d4ra08429b. eCollection 2025 Mar 17.

DOI:10.1039/d4ra08429b
PMID:40103977
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11915085/
Abstract

This review discusses the extraction of critical metals (Li, Co, and Ni) using ionic liquids. Here, ionic liquids act as solvents for the separation and extraction of metals. In addition to extraction, they can be used as a lixiviant to leach out metals from spent lithium-ion batteries. Leaching and extraction of metals from the leachate can be performed using a single ionic liquid solvent. Lithium, cobalt, and nickel have been discussed in detail as per their reactivity towards an ionic liquid based on the extraction efficiency and reusability of the ionic liquid. Recycling and reusability of ionic liquids are crucial parameters to be considered while using them as solvents for extracting metals. Moreover, all the other methods such as solvent extraction, ion exchange, ionic liquids, and DES-based separation of metals are compared with respect to their extraction efficiency, cost-effectiveness, and reusability.

摘要

本综述讨论了使用离子液体提取关键金属（锂、钴和镍）的方法。在这里，离子液体作为分离和提取金属的溶剂。除了提取之外，它们还可以用作浸出剂，从废旧锂离子电池中浸出金属。可以使用单一离子液体溶剂从浸出液中浸出和提取金属。根据离子液体的提取效率和可重复使用性，详细讨论了锂、钴和镍对离子液体的反应性。在将离子液体用作金属提取溶剂时，其回收利用和可重复使用性是需要考虑的关键参数。此外，还比较了溶剂萃取、离子交换、离子液体和基于DES的金属分离等所有其他方法的提取效率、成本效益和可重复使用性。

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