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离子液体:用于能量转换和存储应用的环境可持续材料。

Ionic liquids: environmentally sustainable materials for energy conversion and storage applications.

机构信息

Department of Applied Chemistry (CBFS - ASAS), Amity University Gurugram, Manesar, Panchgaon, Haryana, 122413, Gurugram, India.

Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi, 221 005, U.P., India.

出版信息

Environ Sci Pollut Res Int. 2024 Feb;31(7):10296-10316. doi: 10.1007/s11356-023-25468-w. Epub 2023 Jan 31.

Abstract

Ionic liquids (ILs), often known as green designer solvents, have demonstrated immense application potential in numerous scientific and technological domains. ILs possess high boiling point and low volatility that make them suitable environmentally benign candidates for many potential applications. The more important aspect associated with ILs is that their physicochemical properties can be effectively changed for desired applications just by tuning the structure of the cationic and/or anionic part of ILs. Furthermore, these eco-friendly designer materials can function as electrolytes or solvents depending on the application. Owing to the distinctive properties such as low volatility, high thermal and electrochemical stability, and better ionic conductivity, ILs are nowadays immensely used in a variety of energy applications, particularly in the development of green and sustainable energy storage and conversion devices. Suitable ILs are designed for specific purposes to be used as electrolytes and/or solvents for fuel cells, lithium-ion batteries, supercapacitors (SCs), and solar cells. Herein, we have highlighted the utilization of ILs as unique green designer materials in Li-batteries, fuel cells, SCs, and solar cells. This review will enlighten the promising prospects of these unique, environmentally sustainable materials for next-generation green energy conversion and storage devices. Ionic liquids have much to offer in the field of energy sciences regarding fixing some of the world's most serious issues. However, most of the discoveries discussed in this review article are still at the laboratory research scale for further development. This review article will inspire researchers and readers about how ILs can be effectively applied in energy sectors for various applications as mentioned above.

摘要

离子液体(ILs),通常被称为绿色设计溶剂,在许多科学和技术领域显示出巨大的应用潜力。ILs 具有高沸点和低挥发性,使其成为许多潜在应用的环境友好型候选物。与 ILs 相关的更重要的方面是,它们的物理化学性质可以通过调整阳离子和/或阴离子部分的结构来有效地为所需的应用进行改变。此外,这些环保型设计材料可以根据应用情况用作电解质或溶剂。由于具有低挥发性、高热稳定性和电化学稳定性以及更好的离子导电性等独特性质,ILs 如今在各种能源应用中得到了广泛的应用,特别是在绿色和可持续能源存储和转换设备的开发中。根据特定用途设计合适的 ILs,用作燃料电池、锂离子电池、超级电容器(SCs)和太阳能电池的电解质和/或溶剂。在此,我们强调了 ILs 作为独特的绿色设计材料在 Li 电池、燃料电池、SCs 和太阳能电池中的应用。本综述将阐明这些独特的、环境可持续的材料在下一代绿色能源转换和存储设备中的广阔前景。离子液体在能源科学领域有很多优势,可以解决世界上一些最严重的问题。然而,本文讨论的大多数发现仍处于实验室研究阶段,有待进一步发展。本文综述将激发研究人员和读者思考如何有效地将 ILs 应用于能源领域,以满足上述各种应用的需求。

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