Evaluation of Leaching Characteristics of Heavy Metal Ions from Red Mud-Graphite Tailings.

The rapid growth of aluminum and graphite industries has generated substantial stockpiles of red mud and graphite tailings, which pose environmental risks due to their high heavy metal content and potential for soil and water contamination. This study investigated the leaching behavior of heavy metals from these materials post-stabilization using cement and a sulfonated oil-based ion curing agent, thereby evaluating their suitability for safe reuse. Semi-dynamic leaching experiments were employed to measure heavy metal release, supplemented by kinetic modeling to discern key leaching mechanisms. The findings indicated that the heavy metal concentrations in leachates were consistently below regulatory standards, with leaching dynamics influenced by dual mechanisms: the diffusion of ions and surface chemical reactions. A diffusion coefficient-based analysis further suggested low leachability indices for all metals, confirming effective immobilization. These results suggest that cement and curing agent-stabilized red mud-graphite tailing composites reduce environmental risks and possess characteristics favorable for resource recovery, thus supporting their sustainable use in industrial applications.