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塑料的生物催化循环利用:事实与虚构

Biocatalytic recycling of plastics: facts and fiction.

作者信息

Zimmermann Wolfgang

机构信息

Leipzig University, Institute of Analytical Chemistry Johannisallee 29 04103 Leipzig Germany

出版信息

Chem Sci. 2025 Mar 31;16(16):6573-6582. doi: 10.1039/d5sc00083a. eCollection 2025 Apr 16.

DOI:10.1039/d5sc00083a
PMID:40171028
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11955835/
Abstract

Due to the lack of efficient end-of-life management, the mass production of plastics has resulted in serious environmental problems. Sustainable biological approaches using enzymes to degrade and recycle plastic waste are emerging as a complement to conventional methods to promote a circular economy of plastics. Only a fraction of the plastic waste generated is currently suitable for biocatalytic deconstruction and the development of economically and environmentally competitive processes is still pending. Inconsistent claims about new plastic-degrading enzymes reveal a need for robust and standardized analysis methods to ensure reproducible results and a realistic evaluation of their potential. This paper critically reviews enzymatic synthetic polymer degradation and its recycling challenges.

摘要

由于缺乏有效的寿命终结管理,塑料的大规模生产已导致严重的环境问题。利用酶降解和回收塑料废物的可持续生物方法正在兴起,作为传统方法的补充,以促进塑料的循环经济。目前,所产生的塑料废物中只有一小部分适合进行生物催化解构,经济和环境竞争力强的工艺仍有待开发。关于新型塑料降解酶的说法不一,这表明需要强大且标准化的分析方法,以确保结果的可重复性,并对其潜力进行现实评估。本文批判性地综述了酶促合成聚合物降解及其回收面临的挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59b5/12001893/fb03857b11af/d5sc00083a-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59b5/12001893/7b9723257a36/d5sc00083a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59b5/12001893/ef8230adfdfd/d5sc00083a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59b5/12001893/fb03857b11af/d5sc00083a-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59b5/12001893/7b9723257a36/d5sc00083a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59b5/12001893/ef8230adfdfd/d5sc00083a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59b5/12001893/fb03857b11af/d5sc00083a-p1.jpg

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Effects of Microplastic Exposure on Human Digestive, Reproductive, and Respiratory Health: A Rapid Systematic Review.微塑料暴露对人类消化、生殖和呼吸健康的影响:一项快速系统评价
Environ Sci Technol. 2024 Dec 31;58(52):22843-22864. doi: 10.1021/acs.est.3c09524. Epub 2024 Dec 18.
2
Pathways to reduce global plastic waste mismanagement and greenhouse gas emissions by 2050.到2050年减少全球塑料垃圾管理不善和温室气体排放的途径。
Science. 2024 Dec 6;386(6726):1168-1173. doi: 10.1126/science.adr3837. Epub 2024 Nov 14.
3
Revisiting the activity of two poly(vinyl chloride)- and polyethylene-degrading enzymes.
重新审视两种聚氯乙烯和聚乙烯降解酶的活性。
Nat Commun. 2024 Oct 1;15(1):8501. doi: 10.1038/s41467-024-52665-z.
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Chemo-Enzymatic Depolymerization of Functionalized Low-Molecular-Weight Polyethylene.功能化低分子量聚乙烯的化学酶解聚
Angew Chem Int Ed Engl. 2024 Dec 9;63(50):e202415012. doi: 10.1002/anie.202415012. Epub 2024 Nov 1.
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Plastic-eating bacteria boost growing business of bioremediation.以塑料为食的细菌推动了生物修复行业的蓬勃发展。
Nat Biotechnol. 2024 Oct;42(10):1481-1485. doi: 10.1038/s41587-024-02401-1.
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An overview on polyurethane-degrading enzymes.聚氨酯降解酶概述。
Biotechnol Adv. 2024 Dec;77:108439. doi: 10.1016/j.biotechadv.2024.108439. Epub 2024 Sep 4.
7
Engineered polyethylene terephthalate hydrolases: perspectives and limits.工程化聚对苯二甲酸乙二醇酯水解酶:展望与局限。
Appl Microbiol Biotechnol. 2024 Jul 2;108(1):404. doi: 10.1007/s00253-024-13222-2.
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