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低强度超声对2219铝合金晶粒细化及异质形核机制的影响

Effect of low-intensity ultrasound on grain refinement and heterogeneous nucleation mechanism of 2219 Al alloy.

作者信息

Li Anqing, Jiang Ripeng, Li Ruiqing, Fu Aolei, Zhang Li, Zhang Lihua

机构信息

Light Alloy Research Institutes, Central South University, Changsha, China; State Key Laboratory of Precision Manufacturing for Extreme Service Performance, Central South University, Changsha, China.

School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, China.

出版信息

Ultrason Sonochem. 2025 Jun;117:107341. doi: 10.1016/j.ultsonch.2025.107341. Epub 2025 Apr 2.

Abstract

The ultrasonic cavitation and acoustic streaming have long been regarded as the dominant mechanisms for refining the solidification microstructure of Aluminum (Al) alloys. This work investigated the effects of low-intensity ultrasound on the solidification microstructure of 2219 Al alloy by setting an ultrasonic application angle of 15° and with the different depths (30 mm, 70 mm, and 110 mm). The experimental results show that low-intensity ultrasound can also achieve a significant refining effect on the microstructure. Comparative analysis of solidified microstructures across multiple samples revealed, for the first time, that low-intensity ultrasound refines grain morphology primarily through enhanced heterogeneous nucleation. By establishing a theoretical model between acoustic intensity (I) and heterogeneous nucleation energy (ΔG), the required low-intensity acoustic pressure amplitude (P) for heterogeneous nucleation was determined. The calculation results are in good agreement with the experimental conclusions, thereby proposing a new mechanism for ultrasound to improve solidification microstructures. This work demonstrates that the ultrasonic cavitation and acoustic streaming are not necessary conditions for refining grain structures. Low-intensity ultrasound can also promote the refinement of Al alloy grain structures when satisfying the critical nucleation acoustic pressure conditions.

摘要

长期以来,超声空化和声流一直被视为细化铝合金凝固组织的主要机制。本研究通过设置15°的超声施加角度并在不同深度(30毫米、70毫米和110毫米)下,研究了低强度超声对2219铝合金凝固组织的影响。实验结果表明,低强度超声对组织也能达到显著的细化效果。通过对多个样品凝固组织的对比分析,首次发现低强度超声主要通过增强异质形核来细化晶粒形态。通过建立声强(I)与异质形核能量(ΔG)之间的理论模型,确定了异质形核所需的低强度声压幅值(P)。计算结果与实验结论吻合良好,从而提出了超声改善凝固组织的新机制。本研究表明,超声空化和声流并非细化晶粒组织的必要条件。当满足临界形核声压条件时,低强度超声也能促进铝合金晶粒组织的细化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/736d/12003017/2aabfd6b8af1/gr1.jpg

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