Wang Lixia, Gao Wenbo, Li Xiangrong, Zheng Xianfu, Li Xin, Sheng Xia, Liu Yanyan, Song Meirong
College of Science, Henan Agricultural University, Zhengzhou 450002 Henan, China.
College of Science, Henan Agricultural University, Zhengzhou 450002 Henan, China.
J Colloid Interface Sci. 2025 Aug 15;692:137496. doi: 10.1016/j.jcis.2025.137496. Epub 2025 Apr 1.
High-energy-density aqueous filtering capacitors are essential for the conversion of alternating current to direct current in contemporary integrated circuits. Yet their energy density is limited by the 1.23 V decomposition voltage of water. Here, we report an asymmetric electrolyte configuration to effectively suppress water decomposition activity, enabling the development of an aqueous filtering capacitor with a 2 V operating voltage, as well as an ultrahigh areal specific energy density of 4.51 ± 0.26 mF V cm (1.25 ± 0.07 μWh cm) at 120 Hz. This significant energy density value surpasses most reported filtering capacitors with a comparable phase angle of -(75.0 ± 1.0)° (Chi et al., 2017; Park et al., 2021; Zhang et al., 2022). Additionally, the capacitor presents outstanding cycling stability with a capacitance retention of 97.9 % after 200,000 cycles. Furthermore, we employ an alternatingly stacked assembly technique to conveniently construct compact and lossless integrated filtering capacitors, enabling efficient alternating current output smoothing from wind generator and ensuring stable power supply for light-controlled circuit. This work substantially advances line filtering electrochemical capacitors toward application in modern circuits.
高能量密度水系滤波电容器对于当代集成电路中交流电到直流电的转换至关重要。然而,它们的能量密度受到水的1.23 V分解电压的限制。在此,我们报告了一种不对称电解质配置,以有效抑制水的分解活性,从而开发出一种工作电压为2 V的水系滤波电容器,以及在120 Hz时具有4.51±0.26 mF V cm²(1.25±0.07 μWh cm²)的超高面积比能量密度。这个显著的能量密度值超过了大多数报道的具有可比相角 -(75.0±1.0)°的滤波电容器(Chi等人,2017年;Park等人,2021年;Zhang等人,2022年)。此外,该电容器具有出色的循环稳定性,在200,000次循环后电容保持率为97.9%。此外,我们采用交替堆叠组装技术,方便地构建紧凑且无损的集成滤波电容器,能够有效地平滑风力发电机的交流输出,并确保为光控电路稳定供电。这项工作极大地推动了线路滤波电化学电容器在现代电路中的应用。