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无裂纹的YSZ陶瓷激光加工:溶剂选择对性能的影响

Laser Processing of YSZ Ceramics without Cracking: The Impact of Solvent Selection on Performance.

作者信息

Usman Muhammad, Katsumata Ken-Ichi, Yamada Tetsuya

机构信息

Future Interdisciplinary Research of Science and Technology, Institute of Innovative Research, Tokyo Institute of Technology, 4259-R2-23 Nagatsuta-cho, Midori-ku, Yokohama-shi, Kanagawa 226-8503, Japan.

Department of Material Science and Technology, Tokyo University of Science, 6-3-1 Niijuku, Katsushika-ku, Tokyo 125-8585, Japan.

出版信息

ACS Omega. 2025 Mar 18;10(12):12192-12199. doi: 10.1021/acsomega.4c10556. eCollection 2025 Apr 1.

Abstract

Efficient thermal management during the laser processing of ceramics is critical to prevent surface damage and maintain structural integrity, especially for materials like Yttria-stabilized zirconia (YSZ), widely used in energy, aerospace, and medical applications. However, the laser processing of YSZ ceramics poses significant challenges related to thermal stress, leading to surface damage and compromised structural performance. This study examines the effects of various cooling media, including water, acetate, and citrate acids, on the surface quality, residual stress, and ablation depth of YSZ ceramics during UV laser processing. Results indicate that acids are the most effective cooling agents, achieving minimal cracking and superior surface quality compared with other conditions. Acid-based cooling reduced the residual stress by up to 84%, enabling shallow and consistent ablation depths. These findings underscore the importance of optimized thermal management to enhance the YSZ processing quality. Potential applications extend to dental ceramics, fuel cells, and aerospace thermal barrier coatings, where enhanced surface integrity is crucial. Future studies should further explore chemical interactions between acid cooling mediums and YSZ to refine laser processing techniques for high-performance applications across industries.

摘要

在陶瓷激光加工过程中,高效的热管理对于防止表面损伤和保持结构完整性至关重要,特别是对于氧化钇稳定氧化锆(YSZ)等材料,其广泛应用于能源、航空航天和医疗领域。然而,YSZ陶瓷的激光加工在热应力方面带来了重大挑战,导致表面损伤和结构性能受损。本研究考察了包括水、醋酸和柠檬酸在内的各种冷却介质对YSZ陶瓷在紫外激光加工过程中的表面质量、残余应力和烧蚀深度的影响。结果表明,酸是最有效的冷却剂,与其他条件相比,能实现最小的开裂和优异的表面质量。基于酸的冷却使残余应力降低了84%,实现了浅且一致的烧蚀深度。这些发现强调了优化热管理对提高YSZ加工质量的重要性。潜在应用扩展到牙科陶瓷、燃料电池和航空航天热障涂层,其中增强表面完整性至关重要。未来的研究应进一步探索酸冷却介质与YSZ之间的化学相互作用,以完善跨行业高性能应用的激光加工技术。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82e0/11966576/b6a3da332595/ao4c10556_0001.jpg

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