Theerthagiri Jayaraman, Karuppasamy K, Lee Seung Jun, Shwetharani R, Kim Hyun-Seok, Pasha S K Khadheer, Ashokkumar Muthupandian, Choi Myong Yong
Core-Facility Center for Photochemistry & Nanomaterials, Department of Chemistry, Research Institute of Natural Sciences, Gyeongsang National University, Jinju, 52828, Republic of Korea.
Division of Electronics and Electrical Engineering, Dongguk University-Seoul, Seoul, 04620, Republic of Korea.
Light Sci Appl. 2022 Aug 10;11(1):250. doi: 10.1038/s41377-022-00904-7.
The global energy crisis is increasing the demand for innovative materials with high purity and functionality for the development of clean energy production and storage. The development of novel photo- and electrocatalysts significantly depends on synthetic techniques that facilitate the production of tailored advanced nanomaterials. The emerging use of pulsed laser in liquid synthesis has attracted immense interest as an effective synthetic technology with several advantages over conventional chemical and physical synthetic routes, including the fine-tuning of size, composition, surface, and crystalline structures, and defect densities and is associated with the catalytic, electronic, thermal, optical, and mechanical properties of the produced nanomaterials. Herein, we present an overview of the fundamental understanding and importance of the pulsed laser process, namely various roles and mechanisms involved in the production of various types of nanomaterials, such as metal nanoparticles, oxides, non-oxides, and carbon-based materials. We mainly cover the advancement of photo- and electrocatalytic nanomaterials via pulsed laser-assisted technologies with detailed mechanistic insights and structural optimization along with effective catalytic performances in various energy and environmental remediation processes. Finally, the future directions and challenges of pulsed laser techniques are briefly underlined. This review can exert practical guidance for the future design and fabrication of innovative pulsed laser-induced nanomaterials with fascinating properties for advanced catalysis applications.
全球能源危机使得对用于清洁能源生产和存储的高纯度、高性能创新材料的需求不断增加。新型光催化剂和电催化剂的开发很大程度上依赖于能够促进定制先进纳米材料生产的合成技术。脉冲激光在液体合成中的新兴应用作为一种有效的合成技术,相较于传统化学和物理合成路线具有诸多优势,包括对尺寸、组成、表面和晶体结构以及缺陷密度的精细调控,且与所制备纳米材料的催化、电子、热、光学和机械性能相关联,因而引起了广泛关注。在此,我们概述了脉冲激光过程的基本理解及其重要性,即涉及各类纳米材料(如金属纳米颗粒、氧化物、非氧化物和碳基材料)生产的各种作用和机制。我们主要介绍了通过脉冲激光辅助技术制备光催化和电催化纳米材料的进展,详细阐述了其作用机理、结构优化以及在各种能源和环境修复过程中的有效催化性能。最后,简要强调了脉冲激光技术的未来发展方向和挑战。本综述可为未来设计和制备具有迷人特性、适用于先进催化应用的创新型脉冲激光诱导纳米材料提供实际指导。