Hakimov Muminjon, Ortikov Ilkhomjon, Sattarov Tulkinjon, Tashkhodjaev Bakhodir, Tojiboev Akmaljon
Namangan State University, Boburshoh str. 161, Namangan, 160107, Uzbekistan.
Alfraganus University, Yukari Karakamysh str. 2A 100190, Tashkent, Uzbekistan.
Acta Crystallogr E Crystallogr Commun. 2025 Mar 4;81(Pt 4):271-274. doi: 10.1107/S2056989025001732. eCollection 2025 Apr 1.
The core of the title complex, di-chlorido-bis-(propyl 4-{[1-(2-methyl-4-nitro-phen-yl)-1-1,2,3-triazol-4-yl]meth-oxy}benzoate)copper(II), [CuCl(CHNO)], which belongs to the copper(II) complex family, consists of two CHNO ligands and two chloride ligands arranged around the metal, forming a -di-chlorido square-planar complex. In the crystal, the mol-ecules are linked by C-H⋯Cl and C-H⋯O hydrogen bonds as well as by aromatic π-π stacking inter-actions into a three-dimensional network. To further analyse the inter-molecular inter-actions, a Hirshfeld surface analysis was performed.
标题配合物二氯双(4-{[1-(2-甲基-4-硝基苯基)-1H-1,2,3-三唑-4-基]甲氧基}苯甲酸丙酯)铜(II),[CuCl₂(C₂₀H₁₅N₄O₃)₂],属于铜(II)配合物家族,其核心由两个C₂₀H₁₅N₄O₃配体和两个氯配体围绕金属排列组成,形成一个二氯平面正方形配合物。在晶体中,分子通过C-H⋯Cl和C-H⋯O氢键以及芳香π-π堆积相互作用连接成三维网络。为了进一步分析分子间相互作用,进行了 Hirshfeld 表面分析。