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4-{[1-(2-甲基-4-硝基苯基)-1,2,3-三唑-4-基]甲氧基}苯甲酸丙酯氯化铜(II)配合物的合成、晶体结构及 Hirshfeld 表面分析

Synthesis, crystal structure and Hirshfeld surface analysis of a propyl 4-{[1-(2-methyl-4-nitro-phen-yl)-1-1,2,3-triazol-4-yl]meth-oxy}benzoate copper(II) chloride complex.

作者信息

Hakimov Muminjon, Ortikov Ilkhomjon, Sattarov Tulkinjon, Tashkhodjaev Bakhodir, Tojiboev Akmaljon

机构信息

Namangan State University, Boburshoh str. 161, Namangan, 160107, Uzbekistan.

Alfraganus University, Yukari Karakamysh str. 2A 100190, Tashkent, Uzbekistan.

出版信息

Acta Crystallogr E Crystallogr Commun. 2025 Mar 4;81(Pt 4):271-274. doi: 10.1107/S2056989025001732. eCollection 2025 Apr 1.

Abstract

The core of the title complex, di-chlorido-bis-(propyl 4-{[1-(2-methyl-4-nitro-phen-yl)-1-1,2,3-triazol-4-yl]meth-oxy}benzoate)copper(II), [CuCl(CHNO)], which belongs to the copper(II) complex family, consists of two CHNO ligands and two chloride ligands arranged around the metal, forming a -di-chlorido square-planar complex. In the crystal, the mol-ecules are linked by C-H⋯Cl and C-H⋯O hydrogen bonds as well as by aromatic π-π stacking inter-actions into a three-dimensional network. To further analyse the inter-molecular inter-actions, a Hirshfeld surface analysis was performed.

摘要

标题配合物二氯双(4-{[1-(2-甲基-4-硝基苯基)-1H-1,2,3-三唑-4-基]甲氧基}苯甲酸丙酯)铜(II),[CuCl₂(C₂₀H₁₅N₄O₃)₂],属于铜(II)配合物家族,其核心由两个C₂₀H₁₅N₄O₃配体和两个氯配体围绕金属排列组成,形成一个二氯平面正方形配合物。在晶体中,分子通过C-H⋯Cl和C-H⋯O氢键以及芳香π-π堆积相互作用连接成三维网络。为了进一步分析分子间相互作用,进行了 Hirshfeld 表面分析。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/66c8/11974326/92a54b611eb8/e-81-00271-fig1.jpg

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