Ahmad Ishfaq, Mahmood Javeed, Baek Jong-Beom
School of Energy and Chemical Engineering/Center for Dimension-Controllable Organic Frameworks Ulsan National Institute of Science and Technology (UNIST) UNIST 50 Ulsan 44919 Republic of Korea.
Small Sci. 2020 Oct 21;1(1):2000007. doi: 10.1002/smsc.202000007. eCollection 2021 Jan.
Porous materials are ubiquitous in nature and play central roles in ecosystems and human life. Porous fused aromatic networks (P-FANs) are emerging as a new class of porous organic materials, which can be precisely constructed from organic precursors via the formation of irreversible fused aromatic rings. Despite the luculent advantages offered by P-FANs, the research community has conventionally focused on more synthetically accessible covalent organic frameworks (COFs), which mostly involve reversible condensation reactions. An overview of the trend in the field of P-FANs and their possible applications in different fields, including proton conduction, catalysis, gas storage, supercapacitors, and optoelectronics, is presented herein.
多孔材料在自然界中无处不在,在生态系统和人类生活中发挥着核心作用。多孔稠合芳环网络(P-FANs)正作为一类新型的多孔有机材料崭露头角,它可以通过不可逆稠合芳环的形成由有机前体精确构建而成。尽管P-FANs具有明显的优势,但传统上研究界更多地关注合成上更容易获得的共价有机框架(COFs),其大多涉及可逆缩合反应。本文概述了P-FANs领域的发展趋势及其在不同领域的可能应用,包括质子传导、催化、气体存储、超级电容器和光电子学。