• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

共价有机框架用于高级应用的机遇

Opportunities of Covalent Organic Frameworks for Advanced Applications.

作者信息

Song Yanpei, Sun Qi, Aguila Briana, Ma Shengqian

机构信息

Department of Chemistry University of South Florida 4202 E Fowler Ave. Tampa FL 33620 USA.

出版信息

Adv Sci (Weinh). 2018 Nov 12;6(2):1801410. doi: 10.1002/advs.201801410. eCollection 2019 Jan 23.

DOI:10.1002/advs.201801410
PMID:30693185
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6343072/
Abstract

Covalent organic frameworks (COFs) are an emerging class of functional nanostructures with intriguing properties, due to their unprecedented combination of high crystallinity, tunable pore size, large surface area, and unique molecular architecture. The range of properties characterized in COFs has rapidly expanded to include those of interest for numerous applications ranging from energy to environment. Here, a background overview is provided, consisting of a brief introduction of porous materials and the design feature of COFs. Then, recent advancements of COFs as a designer platform for a plethora of applications are emphasized together with discussions about the strategies and principles involved. Finally, challenges remaining for this type material for real applications are outlined.

摘要

共价有机框架（COFs）是一类新兴的功能性纳米结构，具有引人注目的特性，这归因于它们前所未有的高结晶度、可调孔径、大表面积和独特分子结构的组合。COFs所具有的一系列特性已迅速扩展，涵盖了从能源到环境等众多应用领域中令人感兴趣的特性。在此，提供一个背景概述，包括对多孔材料的简要介绍以及COFs的设计特点。然后，强调了COFs作为用于众多应用的设计平台的最新进展，并讨论了其中涉及的策略和原理。最后，概述了这类材料在实际应用中仍然存在的挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/ca519ecbb9f6/ADVS-6-1801410-g028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/6eb187705d3a/ADVS-6-1801410-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/a3e1aad3cdd1/ADVS-6-1801410-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/350a7130045a/ADVS-6-1801410-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/b3b9464571df/ADVS-6-1801410-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/29c2f0e49e5c/ADVS-6-1801410-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/039eae473ccb/ADVS-6-1801410-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/5d8cab84aed1/ADVS-6-1801410-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/71f205cb04ef/ADVS-6-1801410-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/cd9162619c7a/ADVS-6-1801410-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/0200fd6743b8/ADVS-6-1801410-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/08732de662eb/ADVS-6-1801410-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/f69fea27f73c/ADVS-6-1801410-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/58fbd11cdeaa/ADVS-6-1801410-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/6a17d398ef53/ADVS-6-1801410-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/5b8868d33f5a/ADVS-6-1801410-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/f2bd363740cb/ADVS-6-1801410-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/ee9afc87e025/ADVS-6-1801410-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/1609931cda5c/ADVS-6-1801410-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/d62ed3a4e7ef/ADVS-6-1801410-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/afb9df371cc5/ADVS-6-1801410-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/34b6eb87da7d/ADVS-6-1801410-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/d24c5c8b686a/ADVS-6-1801410-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/601ad959dae3/ADVS-6-1801410-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/272a0f610f98/ADVS-6-1801410-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/096d0172a21b/ADVS-6-1801410-g025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/6d48297e03ce/ADVS-6-1801410-g026.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/1a494594b8fe/ADVS-6-1801410-g027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/ca519ecbb9f6/ADVS-6-1801410-g028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/6eb187705d3a/ADVS-6-1801410-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/a3e1aad3cdd1/ADVS-6-1801410-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/350a7130045a/ADVS-6-1801410-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/b3b9464571df/ADVS-6-1801410-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/29c2f0e49e5c/ADVS-6-1801410-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/039eae473ccb/ADVS-6-1801410-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/5d8cab84aed1/ADVS-6-1801410-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/71f205cb04ef/ADVS-6-1801410-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/cd9162619c7a/ADVS-6-1801410-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/0200fd6743b8/ADVS-6-1801410-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/08732de662eb/ADVS-6-1801410-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/f69fea27f73c/ADVS-6-1801410-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/58fbd11cdeaa/ADVS-6-1801410-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/6a17d398ef53/ADVS-6-1801410-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/5b8868d33f5a/ADVS-6-1801410-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/f2bd363740cb/ADVS-6-1801410-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/ee9afc87e025/ADVS-6-1801410-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/1609931cda5c/ADVS-6-1801410-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/d62ed3a4e7ef/ADVS-6-1801410-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/afb9df371cc5/ADVS-6-1801410-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/34b6eb87da7d/ADVS-6-1801410-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/d24c5c8b686a/ADVS-6-1801410-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/601ad959dae3/ADVS-6-1801410-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/272a0f610f98/ADVS-6-1801410-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/096d0172a21b/ADVS-6-1801410-g025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/6d48297e03ce/ADVS-6-1801410-g026.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/1a494594b8fe/ADVS-6-1801410-g027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8147/6343072/ca519ecbb9f6/ADVS-6-1801410-g028.jpg

相似文献

1
Opportunities of Covalent Organic Frameworks for Advanced Applications.共价有机框架用于高级应用的机遇
Adv Sci (Weinh). 2018 Nov 12;6(2):1801410. doi: 10.1002/advs.201801410. eCollection 2019 Jan 23.
2
Integration of Enzyme and Covalent Organic Frameworks: From Rational Design to Applications.酶与共价有机框架的整合：从合理设计到应用。
Acc Chem Res. 2024 Jan 2;57(1):93-105. doi: 10.1021/acs.accounts.3c00565. Epub 2023 Dec 17.
3
Covalent Organic Frameworks: From Materials Design to Biomedical Application.共价有机框架：从材料设计到生物医学应用
Nanomaterials (Basel). 2017 Dec 28;8(1):15. doi: 10.3390/nano8010015.
4
Covalent Organic Frameworks: A Promising Materials Platform for Photocatalytic CO Reductions.共价有机框架材料：用于光催化 CO 还原的有前途的材料平台。
Molecules. 2020 May 22;25(10):2425. doi: 10.3390/molecules25102425.
5
Composite materials based on covalent organic frameworks for multiple advanced applications.基于共价有机框架的复合材料用于多种先进应用。
Exploration (Beijing). 2023 May 23;3(3):20220144. doi: 10.1002/EXP.20220144. eCollection 2023 Jun.
6
Covalent Organic Frameworks for CO2 Capture.用于二氧化碳捕获的共价有机框架。
Adv Mater. 2016 Apr 20;28(15):2855-73. doi: 10.1002/adma.201505004. Epub 2016 Feb 29.
7
Covalent organic frameworks (COFs) as carrier for improved drug delivery and biosensing applications.共价有机框架（COFs）作为载体用于改善药物传递和生物传感应用。
Biotechnol Bioeng. 2024 Jul;121(7):2017-2049. doi: 10.1002/bit.28718. Epub 2024 Apr 25.
8
Large-Scale Synthesis of Covalent Organic Frameworks: Challenges and Opportunities.共价有机框架的大规模合成：挑战与机遇
Membranes (Basel). 2023 Jul 27;13(8):696. doi: 10.3390/membranes13080696.
9
Two-dimensional covalent organic frameworks with hierarchical porosity.具有分级孔隙率的二维共价有机框架
Chem Soc Rev. 2020 Jun 21;49(12):3920-3951. doi: 10.1039/d0cs00049c. Epub 2020 May 19.
10
[Research progress on preparation and applications of covalent organic framework-based chromatographic stationary phases].基于共价有机框架的色谱固定相的制备及应用研究进展
Se Pu. 2023 Oct;41(10):843-852. doi: 10.3724/SP.J.1123.2023.04021.

引用本文的文献

1
Crystalline Covalent Organic Framework Paper for Sweating Disorder Disease Analysis.用于多汗症疾病分析的结晶共价有机框架纸
ACS Omega. 2025 Aug 16;10(33):37803-37814. doi: 10.1021/acsomega.5c04646. eCollection 2025 Aug 26.
2
Toward Continuous, Oriented Covalent Organic Framework Membranes for Precise Molecular Separations.迈向用于精确分子分离的连续、定向共价有机框架膜。
ACS Nano. 2025 Aug 26;19(33):29934-29960. doi: 10.1021/acsnano.5c09252. Epub 2025 Aug 15.
3
Creating electrochemical accessibility in covalent organic frameworks for uranium extraction via electrodeposition.

本文引用的文献

1
Synthesis of Benzobisoxazole-Linked Two-Dimensional Covalent Organic Frameworks and Their Carbon Dioxide Capture Properties.苯并双恶唑连接的二维共价有机框架的合成及其二氧化碳捕获性能。
ACS Macro Lett. 2016 Sep 20;5(9):1055-1058. doi: 10.1021/acsmacrolett.6b00486. Epub 2016 Sep 6.
2
Hydrazone-based covalent organic frameworks for Lewis acid catalysis.基于腙的共价有机框架用于路易斯酸催化。
Dalton Trans. 2018 Oct 9;47(39):13824-13829. doi: 10.1039/c8dt03005g.
3
Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks.
通过电沉积在共价有机框架中创造用于铀萃取的电化学可及性。
Nat Commun. 2025 Aug 2;16(1):7093. doi: 10.1038/s41467-025-62501-7.
4
Creating free standing covalent organic framework membranes by nanocrystal suturing in sol gel solutions.通过在溶胶-凝胶溶液中进行纳米晶体缝合来制备独立的共价有机框架膜。
Nat Commun. 2025 Jul 1;16(1):5712. doi: 10.1038/s41467-025-61325-9.
5
Pore engineering in metal-organic frameworks and covalent organic frameworks: strategies and applications.金属有机框架和共价有机框架中的孔工程：策略与应用
Chem Sci. 2025 Jun 14. doi: 10.1039/d5sc01635e.
6
Rapid Formation of Vinylene-Linked Covalent Organic Frameworks Promoted by Dipole Moment.偶极矩促进亚乙烯基连接的共价有机框架的快速形成
Chem Mater. 2025 Feb 18;37(5):1923-1934. doi: 10.1021/acs.chemmater.4c03161. eCollection 2025 Mar 11.
7
Biochar-mediated carbon nitride and covalent organic framework photocatalyst for enhanced tetracycline degradation.生物炭介导的氮化碳与共价有机框架光催化剂用于增强四环素降解
RSC Adv. 2025 May 27;15(22):17491-17502. doi: 10.1039/d5ra01986a. eCollection 2025 May 21.
8
Local Charge Density Enhancement Strategy in Nitrogen-rich Covalent Organic Framework for Boosted Iodine Removal From Water.富氮共价有机框架中用于增强水中碘去除的局部电荷密度增强策略
Adv Sci (Weinh). 2025 Aug;12(30):e00697. doi: 10.1002/advs.202500697. Epub 2025 May 20.
9
Next-Generation Chromatography: Covalent Organic Frameworks in Biomedical Analysis.下一代色谱法：生物医学分析中的共价有机框架
J Sep Sci. 2025 Apr;48(4):e70148. doi: 10.1002/jssc.70148.
10
Recent Progress in Porous Fused Aromatic Networks and Their Applications.多孔稠合芳香网络及其应用的最新进展
Small Sci. 2020 Oct 21;1(1):2000007. doi: 10.1002/smsc.202000007. eCollection 2021 Jan.
将亚胺共价有机骨架转化为超稳定结晶多孔芳香骨架的简便方法。
Nat Commun. 2018 Jul 31;9(1):2998. doi: 10.1038/s41467-018-05462-4.
4
Rational Design of MOF/COF Hybrid Materials for Photocatalytic H Evolution in the Presence of Sacrificial Electron Donors.用于在牺牲电子供体存在下光催化析氢的金属有机框架/共价有机框架杂化材料的合理设计
Angew Chem Int Ed Engl. 2018 Sep 10;57(37):12106-12110. doi: 10.1002/anie.201806862. Epub 2018 Aug 7.
5
Water-dispersible PEG-curcumin/amine-functionalized covalent organic framework nanocomposites as smart carriers for in vivo drug delivery.水散性 PEG-姜黄素/胺功能化共价有机骨架纳米复合材料作为体内药物输送的智能载体。
Nat Commun. 2018 Jul 17;9(1):2785. doi: 10.1038/s41467-018-04910-5.
6
Highly Conjugated Three-Dimensional Covalent Organic Frameworks Based on Spirobifluorene for Perovskite Solar Cell Enhancement.基于螺二芴的高度共轭三维共价有机框架用于增强钙钛矿太阳能电池
J Am Chem Soc. 2018 Aug 8;140(31):10016-10024. doi: 10.1021/jacs.8b06291. Epub 2018 Jul 27.
7
Conversion of Imine to Oxazole and Thiazole Linkages in Covalent Organic Frameworks.共价有机框架中亚胺向恶唑和噻唑键的转化
J Am Chem Soc. 2018 Jul 25;140(29):9099-9103. doi: 10.1021/jacs.8b05830. Epub 2018 Jul 12.
8
Single-crystal x-ray diffraction structures of covalent organic frameworks.共价有机框架的单晶 X 射线衍射结构。
Science. 2018 Jul 6;361(6397):48-52. doi: 10.1126/science.aat7679.
9
Surface Pore Engineering of Covalent Organic Frameworks for Ammonia Capture through Synergistic Multivariate and Open Metal Site Approaches.通过协同多变量和开放金属位点方法对共价有机框架进行表面孔工程以捕获氨
ACS Cent Sci. 2018 Jun 27;4(6):748-754. doi: 10.1021/acscentsci.8b00232. Epub 2018 Jun 6.
10
Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis.通过原位反应将亚胺转化为噻唑连接的共价有机框架，实现真实结构分析。
Nat Commun. 2018 Jul 3;9(1):2600. doi: 10.1038/s41467-018-04979-y.