• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

用于锂电池的高压电解质化学

High-Voltage Electrolyte Chemistry for Lithium Batteries.

作者信息

Guo Kanglong, Qi Shihan, Wang Huaping, Huang Junda, Wu Mingguang, Yang Yulu, Li Xiu, Ren Yurong, Ma Jianmin

机构信息

School of Materials and Energy University of Electronic Science and Technology of China Chengdu Sichuan 611731 China.

School of Physics and Electronics Hunan University Changsha 410082 Hunan China.

出版信息

Small Sci. 2022 Feb 18;2(5):2100107. doi: 10.1002/smsc.202100107. eCollection 2022 May.

DOI:10.1002/smsc.202100107
PMID:40212600
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11935967/
Abstract

Lithium batteries are currently the most popular and promising energy storage system, but the current lithium battery technology can no longer meet people's demand for high energy density devices. Increasing the charge cutoff voltage of a lithium battery can greatly increase its energy density. However, as the voltage increases, a series of unfavorable factors emerges in the system, causing the rapid failure of lithium batteries. To overcome these problems and extend the life of high-voltage lithium batteries, electrolyte modification strategies have been widely adopted. Under this content, this review first introduces the degradation mechanism of lithium batteries under high cutoff voltage, and then presents an overview of the recent progress in the modification of high-voltage lithium batteries using electrolyte modification strategies. Finally, the future direction of high-voltage lithium battery electrolytes is also proposed.

摘要

锂电池是目前最流行且最具前景的储能系统，但当前的锂电池技术已无法满足人们对高能量密度设备的需求。提高锂电池的充电截止电压可大幅提升其能量密度。然而，随着电压升高，系统中会出现一系列不利因素，导致锂电池迅速失效。为克服这些问题并延长高压锂电池的寿命，电解质改性策略已被广泛采用。在此背景下，本综述首先介绍了锂电池在高截止电压下的降解机制，然后概述了采用电解质改性策略对高压锂电池进行改性的近期进展。最后，还提出了高压锂电池电解质的未来发展方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/b428ca4c9a18/SMSC-2-2100107-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/3f45188a6d14/SMSC-2-2100107-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/16b1fee49e79/SMSC-2-2100107-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/16bfec3b94dd/SMSC-2-2100107-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/08529ea98cd0/SMSC-2-2100107-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/6890ddd1f9c4/SMSC-2-2100107-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/c5ebd491b1a5/SMSC-2-2100107-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/512d1dea2c9a/SMSC-2-2100107-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/2020c2090e50/SMSC-2-2100107-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/b04ad33476f4/SMSC-2-2100107-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/caffee58a4cd/SMSC-2-2100107-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/b428ca4c9a18/SMSC-2-2100107-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/3f45188a6d14/SMSC-2-2100107-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/16b1fee49e79/SMSC-2-2100107-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/16bfec3b94dd/SMSC-2-2100107-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/08529ea98cd0/SMSC-2-2100107-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/6890ddd1f9c4/SMSC-2-2100107-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/c5ebd491b1a5/SMSC-2-2100107-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/512d1dea2c9a/SMSC-2-2100107-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/2020c2090e50/SMSC-2-2100107-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/b04ad33476f4/SMSC-2-2100107-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/caffee58a4cd/SMSC-2-2100107-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcca/11935967/b428ca4c9a18/SMSC-2-2100107-g009.jpg

相似文献

1
High-Voltage Electrolyte Chemistry for Lithium Batteries.用于锂电池的高压电解质化学
Small Sci. 2022 Feb 18;2(5):2100107. doi: 10.1002/smsc.202100107. eCollection 2022 May.
2
Nanostructured electrolytes for stable lithium electrodeposition in secondary batteries.用于二次电池中稳定锂沉积的纳米结构电解质。
Acc Chem Res. 2015 Nov 17;48(11):2947-56. doi: 10.1021/acs.accounts.5b00427. Epub 2015 Oct 23.
3
Research Progresses of Liquid Electrolytes in Lithium-Ion Batteries.锂离子电池液态电解质的研究进展。
Small. 2023 Feb;19(8):e2205315. doi: 10.1002/smll.202205315. Epub 2022 Dec 5.
4
Electrolyte Design Strategies for Non-Aqueous High-Voltage Potassium-Based Batteries.非水高压钾基电池的电解质设计策略。
Molecules. 2023 Jan 13;28(2):823. doi: 10.3390/molecules28020823.
5
Side Reactions/Changes in Lithium-Ion Batteries: Mechanisms and Strategies for Creating Safer and Better Batteries.锂离子电池的副反应/变化：打造更安全、性能更优电池的机制与策略
Adv Mater. 2024 Jul;36(29):e2401482. doi: 10.1002/adma.202401482. Epub 2024 May 19.
6
Bifunctional Lithium Carboxylate for Stabilizing Both Lithium-Metal Anode and High-Voltage Cathode in Ether Electrolyte.用于稳定醚电解质中锂金属阳极和高压阴极的双功能羧酸锂
ACS Appl Mater Interfaces. 2019 Oct 30;11(43):39715-39721. doi: 10.1021/acsami.9b08703. Epub 2019 Oct 16.
7
Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries.碳酸盐电解质中的硝酸锂溶剂化化学助力高压锂金属电池
Angew Chem Int Ed Engl. 2018 Oct 22;57(43):14055-14059. doi: 10.1002/anie.201807034. Epub 2018 Sep 7.
8
Synergistic Inorganic-Organic Dual-Additive Electrolytes Enable Practical High-Voltage Lithium-Ion Batteries.协同无机-有机双添加剂电解质助力实用型高压锂离子电池。
ACS Appl Mater Interfaces. 2022 Mar 2;14(8):10447-10456. doi: 10.1021/acsami.1c24808. Epub 2022 Feb 18.
9
Enabling Ether-Based Electrolytes for Long Cycle Life of Lithium-Ion Batteries at High Charge Voltage.实现用于锂离子电池在高充电电压下长循环寿命的基于醚的电解质。
ACS Appl Mater Interfaces. 2020 Dec 9;12(49):54893-54903. doi: 10.1021/acsami.0c18177. Epub 2020 Nov 23.
10
Design of Non-Incendive High-Voltage Liquid Electrolyte Formulation for Safe Lithium-Ion Batteries.用于安全锂离子电池的非易燃高压液体电解质配方设计
ChemSusChem. 2022 Feb 18;15(4):e202102546. doi: 10.1002/cssc.202102546. Epub 2021 Dec 23.

本文引用的文献

1
Electrolytes enriched by potassium perfluorinated sulfonates for lithium metal batteries.用于锂金属电池的全氟磺酸钾富集电解质。
Sci Bull (Beijing). 2021 Apr 15;66(7):685-693. doi: 10.1016/j.scib.2020.09.018. Epub 2020 Sep 12.
2
Novel piperidinium-based ionic liquid as electrolyte additive for high voltage lithium-ion batteries.用于高压锂离子电池的新型哌啶基离子液体作为电解质添加剂
RSC Adv. 2021 Apr 22;11(25):15091-15098. doi: 10.1039/d1ra01454d. eCollection 2021 Apr 21.
3
Unveiling the Role of Li Solvation Structures with Commercial Carbonates in the Formation of Solid Electrolyte Interphase for Lithium Metal Batteries.
揭示锂溶剂化结构与商用碳酸盐在锂金属电池固体电解质界面形成中的作用。
Small Methods. 2021 Aug;5(8):e2100441. doi: 10.1002/smtd.202100441. Epub 2021 Jul 3.
4
Antioxidation Mechanism of Highly Concentrated Electrolytes at High Voltage.高浓度电解质在高电压下的抗氧化机制
ACS Appl Mater Interfaces. 2021 Dec 15;13(49):59580-59590. doi: 10.1021/acsami.1c19969. Epub 2021 Dec 1.
5
Low-Density Fluorinated Silane Solvent Enhancing Deep Cycle Lithium-Sulfur Batteries' Lifetime.低密度氟化硅烷溶剂可延长深度循环锂硫电池的使用寿命。
Adv Mater. 2021 Sep;33(38):e2102034. doi: 10.1002/adma.202102034. Epub 2021 Aug 2.
6
Optimizing Electrode/Electrolyte Interphases and Li-Ion Flux/Solvation for Lithium-Metal Batteries with Qua-Functional Heptafluorobutyric Anhydride.用四官能七氟丁酸酐优化锂金属电池的电极/电解质界面及锂离子通量/溶剂化作用
Angew Chem Int Ed Engl. 2021 Sep 13;60(38):20717-20722. doi: 10.1002/anie.202107957. Epub 2021 Aug 15.
7
A Novel Electrolyte Additive Enables High-Voltage Operation of Nickel-Rich Oxide/Graphite Cells.一种新型电解液添加剂使富镍氧化物/石墨电池能够在高电压下运行。
J Phys Chem Lett. 2021 May 13;12(18):4327-4338. doi: 10.1021/acs.jpclett.1c00803. Epub 2021 Apr 30.
8
Synergy Effect of Trimethyl Borate on Protecting High-Voltage Cathode Materials in Dual-Additive Electrolytes.硼酸三甲酯在双添加剂电解质中对高压阴极材料的协同保护作用。
ACS Appl Mater Interfaces. 2021 May 12;13(18):21459-21466. doi: 10.1021/acsami.1c04389. Epub 2021 Apr 27.
9
Sulfur is a New High-Performance Additive toward High-Voltage LiNiCoMnO Cathode: Tiny Amount, Huge Impact.硫是一种用于高压锂镍钴锰阴极的新型高性能添加剂：用量微小，影响巨大。
ACS Appl Mater Interfaces. 2021 Apr 28;13(16):18648-18657. doi: 10.1021/acsami.1c00391. Epub 2021 Apr 16.
10
Gradient Solid Electrolyte Interphase and Lithium-Ion Solvation Regulated by Bisfluoroacetamide for Stable Lithium Metal Batteries.双氟乙酰胺调控的梯度固态电解质界面及锂离子溶剂化作用用于稳定锂金属电池
Angew Chem Int Ed Engl. 2021 Mar 15;60(12):6600-6608. doi: 10.1002/anie.202013993. Epub 2021 Feb 8.