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拓扑材料催化剂的进展、优势与挑战

Progress, Advantages, and Challenges of Topological Material Catalysts.

作者信息

Xie Ruikuan, Zhang Tan, Weng Hongming, Chai Guo-Liang

机构信息

State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 350002 P. R. China.

University of Chinese Academy of Sciences Beijing 100190 P. R. China.

出版信息

Small Sci. 2022 Feb 3;2(4):2100106. doi: 10.1002/smsc.202100106. eCollection 2022 Apr.

Abstract

Topological materials is one of the hottest topics in condensed matter physics because of its exotic properties such as robust metallic boundary states, Fermi arcs, and the spin-momentum-locking helicity. The topologically protected conducting boundary states spanning the whole bandgap are expected to serve as robust and wide-range-energy transition states facilitating catalytic reactions. Recently, some topological materials have been found to be high-performance catalysts, which might open an emerging research field. Herein, an overview of topological materials is given and then recent progress in topological material catalysts (TMCs) is presented. As it is a new field, more detailed and accurate mechanisms behind the high performance of TMCs are urgently needed. Combining theoretical and experimental studies is a promising way to resolve these puzzles. Heterostructures, dopants, and defects have the chance to tune the catalytic activity of TMCs while retaining topological surface states (TSSs). Also, more TMCs are needed to be discovered, and more catalytic reactions are to be investigated for TMCs in the future.

摘要

拓扑材料因其诸如稳健的金属边界态、费米弧以及自旋-动量锁定螺旋性等奇异特性,成为凝聚态物理领域最热门的话题之一。跨越整个带隙的拓扑保护导电边界态有望作为促进催化反应的稳健且宽能量范围的跃迁态。最近,一些拓扑材料已被发现是高性能催化剂,这可能开启一个新兴的研究领域。在此,先对拓扑材料进行概述,然后介绍拓扑材料催化剂(TMCs)的最新进展。由于这是一个新领域,迫切需要更详细、准确地了解TMCs高性能背后的机制。将理论研究与实验研究相结合是解决这些难题的一种很有前景的方法。异质结构、掺杂剂和缺陷有机会在保留拓扑表面态(TSSs)的同时调节TMCs的催化活性。此外,未来还需要发现更多的TMCs,并对其进行更多的催化反应研究。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecf0/11935991/5c25bd1cdede/SMSC-2-2100106-g011.jpg

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