Han Runlin, Liu Zihan, Feng Faxiang, Su Shi, Dong Guilin, Liu Xiaobing, Gu Hongbo
Key Laboratory of Jiangxi Province for Special Optoelectronic Artificial Crystal Materials, School of Chemistry and Chemical Engineering, Jinggangshan University, Ji'an 343009, China.
Key Laboratory of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China.
Polymers (Basel). 2025 Mar 24;17(7):869. doi: 10.3390/polym17070869.
At present, the oil extraction and chemical industry and other industries produce a large amount of oily wastewater and organic sewage, and the world is suffering from oil spills and organic wastewater pollution. As a porous material, aerogels are promising in the field of oil adsorption. In this work, the nanocellulose/aminated multi-walled carbon nanotube (NC-MWCNT-NH) nanocomposite aerogel with a high porosity of up to 97.80% is prepared by varying the weight percentage of MWCNTs-NH, among which the nanocomposite aerogel with 0.1% weight percentage of MWCNTs-NH exhibits the best adsorption performance with the adsorption capacity to cyclohexane, ethyl acetate, anhydrous ethanol, methylene dichloride, acetone, kerosene, pump oil, and used pump oil of 39.77 ± 0.82, 44.54 ± 1.67, 43.03 ± 1.06, 62.13 ± 0.36, 39.92 ± 1.09, 39.37 ± 0.27, 43.48 ± 0.06, and 38.45 ± 0.84 g·g, respectively. Compared with pure nanocellulose aerogel, the adsorption capacity of the NC-MWCNT-NH aerogel to pump oil is improved by up to 93.9%, which exhibits excellent adsorption properties and could be utilized in the field of oil adsorption.
目前,石油开采与化工等行业产生大量含油废水和有机污水,全球正遭受石油泄漏和有机废水污染之苦。气凝胶作为一种多孔材料,在油吸附领域颇具前景。在本工作中,通过改变氨基化多壁碳纳米管(MWCNTs-NH)的重量百分比,制备了孔隙率高达97.80%的纳米纤维素/氨基化多壁碳纳米管(NC-MWCNT-NH)纳米复合气凝胶,其中MWCNTs-NH重量百分比为0.1%的纳米复合气凝胶对环己烷、乙酸乙酯、无水乙醇、二氯甲烷、丙酮、煤油、泵油和废泵油的吸附容量分别为39.77±0.82、44.54±1.67、43.03±1.06、62.13±0.36、39.92±1.09、39.37±0.27、43.48±0.06和38.45±0.84 g·g,表现出最佳吸附性能。与纯纳米纤维素气凝胶相比,NC-MWCNT-NH气凝胶对泵油的吸附容量提高了高达93.9%,展现出优异的吸附性能,可用于油吸附领域。