Wang Huihui, Yi Yuxuan, Wang Guangchao, Zhao Xinhao, Yin Fei
Hubei Longzhong Laboratory, Xiangyang 441000, China.
Hubei Key Laboratory of Advanced Technology for Automotive Components, Wuhan University of Technology, Wuhan 430070, China.
ACS Appl Mater Interfaces. 2025 Apr 30;17(17):25934-25950. doi: 10.1021/acsami.4c22686. Epub 2025 Apr 15.
Ultrasonic shot peening (USP) strengthening represents an emerging and efficient surface mechanical reinforcement technique. 20CrMnTi gear steel is commonly employed engineering material for gear components within vehicular power transmission systems. In this study, a gradient nanostructured (GN) surface layer was successfully fabricated in 20CrMnTi gear steel at room temperature using USP technology. Furthermore, an integrated process combining pre-USP treatment with subsequent carburizing heat treatment (USP-carburized) was implemented, resulting in an approximate increase of 50 HV in surface hardness and an augmentation of the hardened layer depth by roughly 50 μm compared to samples subjected solely to carburizing. OM and EBSD analyses reveal that the pre-USP treatment nearly doubles the carbide density at the surface, while concurrently reducing both the carbide and martensite dimensions by approximately 10%. Additionally, SEM and EDS results demonstrates that the pre-USP process significantly elevates the internal carbon content in 20CrMnTi gear steel after carburizing. The microstructural evolution and promoting mechanism of the GN during the CHT is elucidated in the study. TEM observations indicate that pre-USP treatment induces a pronounced surface nanocrystallization phenomenon where carbon atoms preferentially diffuse into the high angle grain boundaries (HAGBs, θ ≤ 15°) during carburizing, resulting in the carbides inside the carburized 20CrMnTi gear steel distribute along grain boundaries (GBs) accompanied by a high density of dislocations. Consequently, the GN effectively promotes rapid carbon diffusion. This study significantly advances the understanding of the mechanisms by which GN influence the efficacy of carburizing treatments.
超声喷丸强化(USP)是一种新兴的高效表面机械强化技术。20CrMnTi齿轮钢是车辆动力传输系统中齿轮部件常用的工程材料。在本研究中,采用USP技术在室温下成功制备了20CrMnTi齿轮钢的梯度纳米结构(GN)表层。此外,实施了将USP预处理与随后的渗碳热处理相结合的综合工艺(USP渗碳),与仅进行渗碳的样品相比,表面硬度提高了约50 HV,硬化层深度增加了约50μm。金相显微镜(OM)和电子背散射衍射(EBSD)分析表明,USP预处理使表面碳化物密度几乎增加了一倍,同时碳化物和马氏体尺寸均减小了约10%。此外,扫描电子显微镜(SEM)和能谱分析(EDS)结果表明,USP预处理显著提高了渗碳后20CrMnTi齿轮钢的内部碳含量。本研究阐明了渗碳热处理过程中GN的微观结构演变及促进机制。透射电子显微镜(TEM)观察表明,USP预处理引发了明显的表面纳米晶化现象,渗碳过程中碳原子优先扩散到高角度晶界(HAGBs,θ≤15°),导致渗碳20CrMnTi齿轮钢内部的碳化物沿晶界分布,同时伴有高密度位错。因此,GN有效地促进了碳的快速扩散。本研究显著推进了对GN影响渗碳处理效果机制的理解。