Guo Haiyang, He Donglin, Long De-Liang, Cronin Leroy
School of Chemistry, The University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, 314001, P. R. China.
Chem Commun (Camb). 2025 May 8;61(39):7121-7124. doi: 10.1039/d5cc00703h.
A robotic platform was employed to investigate the synthetic conditions for the assembly of molybdenum blue (MB) polyoxometalates in a large chemical space that included concentrations of reactants, the amount of reducing agent, solution pH Four different solid phases of {Mo} MB clusters were identified and crystallographically explored, demonstrating the robotic platform's strength in targeted exploration.
采用一个机器人平台,在包括反应物浓度、还原剂用量、溶液pH值等在内的大化学空间中研究钼蓝(MB)多金属氧酸盐组装的合成条件。鉴定并通过晶体学研究了{Mo} MB簇的四种不同固相,证明了该机器人平台在定向探索方面的优势。