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香豆素作为染料敏化太阳能电池构建用光敏剂应用的最新进展

Recent Advances in the Application of Coumarins as Photosensitizers for the Construction of a Dye-Sensitized Solar Cell.

作者信息

Evangelista Edson, de Jesus Iva S, Pauli Fernanda P, de Souza Acácio S, Borges Amanda de A, Gomes Maria Vitória S F, Ferreira Vitor F, da Silva Fernando de C, Melo Mauricio A, Forezi Luana da S M

机构信息

Departamento de Química Orgânica, Universidade Federal Fluminense - UFF, Niterói, Rio de Janeiro 24020-141, Brazil.

Programa de Pós-Graduação em Química - UFF, Niterói, Rio de Janeiro 24020-141, Brazil.

出版信息

ACS Omega. 2025 Apr 1;10(14):13726-13748. doi: 10.1021/acsomega.4c11135. eCollection 2025 Apr 15.

Abstract

Dye-sensitized solar cells (DSSCs) have emerged as a promising alternative in photovoltaic energy, owing to their efficiency, cost-effectiveness, and versatility. Sensitizers are crucial in efficiently converting solar energy into electricity in these systems. This review focuses on employing coumarins, a class of aromatic organic compounds, as sensitizers in DSSCs. We address the synthesis of coumarins, their photophysical and electronic properties, and their application in optimizing the energy conversion efficiency of DSSCs. We explore the molecular engineering strategies used to improve the properties of coumarins, including structural modification and the combination with other materials. Furthermore, we discuss current challenges and prospects for the development of DSSCs using coumarins as sensitizers. This review aims to provide a comprehensive overview of the current state and future directions of this exciting area of solar energy research.

摘要

染料敏化太阳能电池(DSSC)因其效率、成本效益和多功能性,已成为光伏能源领域一种有前景的替代方案。敏化剂对于在这些系统中将太阳能高效转化为电能至关重要。本综述重点关注将香豆素(一类芳香族有机化合物)用作DSSC中的敏化剂。我们阐述了香豆素的合成、其光物理和电子性质,以及它们在优化DSSC能量转换效率方面的应用。我们探讨了用于改善香豆素性质的分子工程策略,包括结构修饰以及与其他材料的组合。此外,我们讨论了使用香豆素作为敏化剂的DSSC发展的当前挑战和前景。本综述旨在全面概述这一令人兴奋的太阳能研究领域的现状和未来方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f190/12004169/60100461d3f6/ao4c11135_0001.jpg

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