Parmar Vijay S, Gransbury Gemma K, Corner Sophie C, Chou Wei-Hao, Hill Stephen, Winpenny Richard E P, Chilton Nicholas F, Mills David P
Department of Chemistry, School of Natural Sciences, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32310, USA.
Dalton Trans. 2025 May 13;54(19):7616-7620. doi: 10.1039/d5dt00862j.
Two heteroleptic octahedral Dy(III) -aryloxide complexes, [Dy(OPh*)(THF)X] {HOPh* = 2,6-bis(diphenyl-methyl)-4--butylphenol; X = Cl (1), Br (2)}, have been characterised by multi-frequency electron paramagnetic resonance (EPR) spectroscopy to determine = 18.9(1) for 1 and 18.3(6) for 2. These are rare examples of Dy(III) single-molecule magnets that have observable EPR spectra.
两个异配位八面体Dy(III)-芳氧基配合物，[Dy(OPh*)(THF)X] {HOPh* = 2,6-双(二苯基甲基)-4-叔丁基苯酚；X = Cl (1)，Br (2)}，已通过多频电子顺磁共振(EPR)光谱进行了表征，确定1的 值为18.9(1)，2的 值为18.3(6)。这些是具有可观测EPR光谱的Dy(III)单分子磁体的罕见例子。
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