Ma Yusong, Zhao Haoyu, Luo Nian, Chen Feng, Fu Qiang
College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, 610065, P. R. China.
Small. 2025 Jun;21(24):e2502186. doi: 10.1002/smll.202502186. Epub 2025 Apr 25.
The integration of macroscopic and microscopic structural designs plays a crucial role in developing high-performance electromagnetic wave (EMW) absorber devices. In this work, an innovative metamaterial based on a multi-scale design is introduced to address the challenge of narrowband absorption. Specifically, at the microscopic scale, a highly efficient absorbing material (FCIP@SiO@Ppy) is synthesized through an integrated optimization strategy, in which functional layers are uniquely combined to maximize performance. By leveraging heterogeneous interfaces, this design establishes a magneto-electric coupling network, ensuring excellent impedance matching and significantly enhancing the EMW absorption capacity of the material. Notably, the material achieves a record low reflection loss (RL) of -66.66 dB at 9.95 GHz with a broad absorption bandwidth of 5.92 GHz (RL ≤ -10 dB), which is subsequently used to fabricate metamaterial absorber device. Building upon this, at the macroscopic scale, inspired by the compound eye structure of arthropods, a groundbreaking metamaterial structure is proposed. Simulations reveal the achievement of ultra-wideband absorption (2.75-18 GHz) with a remarkably thin thickness of just 12 mm. These pioneering results present effective strategies for the development of next-generation high-performance EMW absorber devices.
宏观和微观结构设计的整合在开发高性能电磁波(EMW)吸收器装置中起着至关重要的作用。在这项工作中,引入了一种基于多尺度设计的创新型超材料,以应对窄带吸收的挑战。具体而言,在微观尺度上,通过一种集成优化策略合成了一种高效吸收材料(FCIP@SiO@Ppy),其中功能层被独特地组合以最大化性能。通过利用异质界面,这种设计建立了一个磁电耦合网络,确保了优异的阻抗匹配,并显著提高了材料的EMW吸收能力。值得注意的是,该材料在9.95 GHz处实现了创纪录的低反射损耗(RL)-66.66 dB,吸收带宽为5.92 GHz(RL≤-10 dB),随后用于制造超材料吸收器装置。在此基础上,在宏观尺度上,受节肢动物复眼结构的启发,提出了一种开创性的超材料结构。模拟结果表明,该结构在仅12 mm的极薄厚度下实现了超宽带吸收(2.75-18 GHz)。这些开创性的结果为开发下一代高性能EMW吸收器装置提供了有效的策略。