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用于去除水中微污染物的创新型吸附剂。

Innovative Sorbents for the Removal of Micropollutants from Water.

作者信息

Solcova Olga, Dlaskova Martina, Kastanek Frantisek

机构信息

Institute of Chemical Process Fundamentals ASCR, v.v.i., Rozvojová 135/1, 16500 Prague, Czech Republic.

出版信息

Molecules. 2025 Mar 24;30(7):1444. doi: 10.3390/molecules30071444.

DOI:10.3390/molecules30071444
PMID:40286024
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11990518/
Abstract

This review summarizes the current knowledge in the field of preparing new and/or innovative materials that can be advantageously used for the sorption of emerging pollutants from water. This paper highlights new innovative materials such as transition metal-modified biochar, zeolites, clays, carbon fibers, graphene, metal organic frameworks, and aerogels. These materials have great potential for the removal of heavy metals from water, particularly due to their large surface area, nanoscale size, and availability of various functionalities; moreover, they can easily be chemically modified and recycled. This paper not only highlights the advantages and ever-improving physicochemical properties of these new types of materials but also critically points out their shortcomings and suggests possible future directions.

摘要

本综述总结了制备新型和/或创新材料领域的当前知识,这些材料可有效地用于从水中吸附新兴污染物。本文重点介绍了新型创新材料,如过渡金属改性生物炭、沸石、粘土、碳纤维、石墨烯、金属有机框架和气凝胶。这些材料在从水中去除重金属方面具有巨大潜力,特别是由于它们具有大表面积、纳米级尺寸以及各种功能基团;此外,它们可以很容易地进行化学改性和回收利用。本文不仅强调了这些新型材料的优点和不断改善的物理化学性质,还批判性地指出了它们的缺点,并提出了可能的未来发展方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/80f4de33b659/molecules-30-01444-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/13fccfc6622b/molecules-30-01444-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/b5211e074f92/molecules-30-01444-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/d03d5e01ad9e/molecules-30-01444-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/a5362f59b34d/molecules-30-01444-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/80f4de33b659/molecules-30-01444-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/13fccfc6622b/molecules-30-01444-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/b5211e074f92/molecules-30-01444-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/d03d5e01ad9e/molecules-30-01444-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/a5362f59b34d/molecules-30-01444-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dcce/11990518/80f4de33b659/molecules-30-01444-g005.jpg

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本文引用的文献

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Graphene aerogels as efficient adsorbers of water pollutants and their effect of drying methods.石墨烯气凝胶作为水污染物的高效吸附剂及其干燥方法的影响。
Sci Rep. 2024 Apr 5;14(1):8029. doi: 10.1038/s41598-024-58651-1.
2
Advances in metal-organic frameworks for water remediation applications.用于水修复应用的金属有机框架材料的进展。
RSC Adv. 2024 Jan 22;14(5):3413-3446. doi: 10.1039/d3ra07982a. eCollection 2024 Jan 17.
3
Bio-Based Aerogels for the Removal of Heavy Metal Ions and Oils from Water: Novel Solutions for Environmental Remediation.
用于去除水中重金属离子和油类的生物基气凝胶:环境修复的新解决方案。
Gels. 2023 Dec 30;10(1):32. doi: 10.3390/gels10010032.
4
Graphene Oxide and Its Derivatives as Adsorbents for PFOA Molecules.氧化石墨烯及其衍生物作为全氟辛酸分子的吸附剂
J Phys Chem B. 2023 Nov 9;127(44):9620-9629. doi: 10.1021/acs.jpcb.3c04762. Epub 2023 Oct 26.
5
Preparation of graphene oxide-doped silica aerogel using supercritical method for efficient removal of emerging pollutants from wastewater.采用超临界法制备氧化石墨烯掺杂二氧化硅气凝胶用于高效去除废水中的新兴污染物
Sci Rep. 2023 Sep 30;13(1):16448. doi: 10.1038/s41598-023-43613-w.
6
Chemical Tailoring of β-Cyclodextrin-Graphene Oxide for Enhanced Per- and Polyfluoroalkyl Substances (PFAS) Adsorption from Drinking Water.用于增强饮用水中全氟和多氟烷基物质(PFAS)吸附的β-环糊精-氧化石墨烯的化学定制
Chemistry. 2023 Oct 26;29(60):e202301854. doi: 10.1002/chem.202301854. Epub 2023 Sep 19.
7
Mn-modified biochars for efficient adsorption and degradation of cephalexin: Insight into the enhanced redox reactivity.锰改性生物炭对头孢氨苄的高效吸附与降解:增强氧化还原反应活性的深入见解。
Water Res. 2023 Sep 1;243:120368. doi: 10.1016/j.watres.2023.120368. Epub 2023 Jul 16.
8
Recent Advances in Nanocellulose Aerogels for Efficient Heavy Metal and Dye Removal.用于高效去除重金属和染料的纳米纤维素气凝胶的最新进展
Gels. 2023 May 16;9(5):416. doi: 10.3390/gels9050416.
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Toxics. 2023 Feb 28;11(3):232. doi: 10.3390/toxics11030232.
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Innovative metal oxides (CaO, SrO, MgO) impregnated waste-derived activated carbon for biohydrogen purification.负载创新型金属氧化物(CaO、SrO、MgO)的废基活性炭用于生物制氢净化。
Sci Rep. 2023 Mar 22;13(1):4705. doi: 10.1038/s41598-023-31723-4.