Peng Youxue, Lei Wen, Yu Wangwang, Chen Yong
College of Science, Nanjing Forestry University, Nanjing 210037, China.
School of Mechanical Engineering, Nanjing Vocational University of Industry Technology, Nanjing 210023, China.
Molecules. 2025 Apr 2;30(7):1583. doi: 10.3390/molecules30071583.
In this study, poly(lactic acid) biocomposites were prepared from sugarcane bagasse (SB) via extrusion and injection molding. The effects of the content and inorganic salt modification of SB on the properties of the biocomposites were investigated. The results showed that the incorporation of SB reduced the biocomposites' mechanical strength and modulus as well as thermal stability but increased their crystallinity, hydrophobicity, and water absorption compared with neat PLA. Among all the biocomposites, the sample containing 30 wt % SB(SB-30/PLA) had the best comprehensive performances, with tensile strength, tensile modulus, flexural strength, and crystallinity values of 31.78 MPa, 219.49 MPa, 53.25 MPa, and 16.8%, respectively. After SB modification with NaSO and MgSO, the increased interfacial adhesion led to a considerable improvement in reinforcement and increases in the flexural strength, flexural modulus, impact strength, and crystallinity of SB-30/PLA; furthermore, the biocomposite became more thermally stable and hydrophobic and contained much less water. In conclusion, SB-30/PLA, especially after MgSO modification, is an ideal degradable biocomposite for applications in packaging, decoration, and other areas.
在本研究中,通过挤出和注塑成型由甘蔗渣(SB)制备了聚乳酸生物复合材料。研究了SB的含量和无机盐改性对生物复合材料性能的影响。结果表明,与纯聚乳酸相比,加入SB降低了生物复合材料的机械强度、模量以及热稳定性,但提高了其结晶度、疏水性和吸水性。在所有生物复合材料中,含30 wt% SB的样品(SB-30/PLA)具有最佳综合性能,其拉伸强度、拉伸模量、弯曲强度和结晶度值分别为31.78 MPa、219.49 MPa、53.25 MPa和16.8%。用NaSO和MgSO对SB进行改性后,界面附着力增强,导致SB-30/PLA的增强效果显著改善,弯曲强度、弯曲模量、冲击强度和结晶度提高;此外,该生物复合材料的热稳定性和疏水性增强,含水量降低。总之,SB-30/PLA,尤其是经MgSO改性后,是一种适用于包装、装饰等领域的理想可降解生物复合材料。