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竹纤维增强聚(丙烯腈-苯乙烯-丙烯腈)/氯化聚乙烯通过相容化。

Bamboo fiber reinforced poly (acrylonitrile-styrene-acrylic)/chlorinated polyethylene via compabilization.

机构信息

Department of Forest Biomaterials, NC State University, Raleigh, NC, USA; Fiber and Biopolymer Research Institute, Department of Plant and Soil Science, Lubbock, TX, USA.

College of Materials Science & Engineering, Nanjing University of Technology, Nanjing, Jiangsu Province, China.

出版信息

Int J Biol Macromol. 2024 May;266(Pt 2):131287. doi: 10.1016/j.ijbiomac.2024.131287. Epub 2024 Mar 31.

Abstract

In the quest to enhance the performance of natural fiber-reinforced polymer composites, achieving optimal dispersion of fiber materials within a polymeric matrix has been identified as a key strategy. Traditional approaches, such as the surface modification of natural fibers, often necessitate the use of additional synthetic chemical processes, presenting a significant challenge. In this work, taking poly (acrylonitrile-styrene-acrylic) (ASA) and bamboo fiber (BF) as a model system, we attempt to use the elastomer-chlorinated polyethylene (CPE) as a compatibilizer to tailor the mechanical properties of ASA/CPE/BF ternary composites. It was found that increasing CPE content contributed to more remarkable reinforcing efficiency, where composite with 15 phr CPE exhibited a nearly four-fold increase in reinforcing efficiency of tensile strength (20 %) compared with that of composite system without CPE (4.1 %). Such improvement was ascribed to the compatibilizing effect exerted by CPE, which prevented the aggregation of BF within polymeric matrix. Surface properties suggested the stronger interface between CPE and BF compared to that between ASA and BF and thereby contributed to the compabilizing effect. Since no chemical process was involved, it is suggested that the introduction of elastomer to be a universal, green and sustainable approach to achieve the reinforcement.

摘要

在提高天然纤维增强聚合物复合材料性能的过程中,实现纤维材料在聚合物基体中的最佳分散已被确定为一项关键策略。传统方法,如天然纤维的表面改性,通常需要使用额外的合成化学工艺,这是一个重大的挑战。在这项工作中,我们以聚(丙烯腈-苯乙烯-丙烯)(ASA)和竹纤维(BF)为模型体系,尝试使用弹性体-氯化聚乙烯(CPE)作为增容剂来调整 ASA/CPE/BF 三元复合材料的机械性能。结果发现,增加 CPE 的含量有助于提高增强效率,其中含有 15phr CPE 的复合材料的拉伸强度增强效率(20%)几乎是没有 CPE 的复合材料系统的四倍(4.1%)。这种改善归因于 CPE 发挥的增容作用,它阻止了 BF 在聚合物基体中的聚集。表面性能表明 CPE 和 BF 之间的界面比 ASA 和 BF 之间的界面更强,从而有助于增容作用。由于没有涉及化学过程,因此建议引入弹性体作为一种通用、绿色和可持续的方法来实现增强。

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