Efficient remediation and synchronous recovery of uranium by phosphate-functionalized magnetic carbon-based flow electrode capacitive deionization.

Through the design of flow electrodes, flow electrode capacitive deionization (FCDI) enables the efficient remediation of uranium-contaminated water to meet World Health Organization (WHO) standards (uranium ≤ 30 ppb), while concurrently facilitating the recovery of uranium from the flow electrode slurry. In this work, the phosphate-functionalized magnetic carbon-based flow electrode (OMPAC) was synthesized by simply co-precipitation and oxygen plasma treatment. The enhanced conductivity of OMPAC accelerated the efficient remediation of surface water contaminated with multiple nuclides, due to the improved charge-transfer capability facilitated by the introduced magnetic particles (Fe, FeO, FeC) and heteroatoms (O, P). The uranium in feed solution was selectively adsorbed by OMPAC in flow electrode slurry, benefiting from the multiple strong sorption interactions between U(VI) and C=O/P=O/P-O groups, as well as the redox reactions between U(VI) and Fe (0/II). After four batch cycles, the average uranium removal rate by OMPAC was maintained at 97.84 %, while the recovery rate of uranium from OMPAC reached 78.2 %, demonstrating the excellent long-term performance and synchronous uranium recovery capability in FCDI. This study provides feasibility guidance for the remediation of radioactive pollution and the strategic reuse of resources via the FCDI technology.