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多酚对简化甘蔗汁模型体系中热致糠醛的抑制机制

Inhibition mechanism of thermally induced furfural in simplified sugarcane juice model system by polyphenols.

作者信息

Zou Weikun, Huang Huimei, Chen Jiebo, Wang Lu

机构信息

People's Government of Kaishan Township, Taining County, Sanming, Fujian Province 354400, China.

National Engineering Research Center of Sugarcane, College of Food Science, Fujian Agriculture and Forestry University, Fuzhou 350002, China.

出版信息

Food Chem X. 2025 Apr 16;27:102469. doi: 10.1016/j.fochx.2025.102469. eCollection 2025 Apr.

Abstract

The inhibitory mechanisms of 5 polyphenols including vanillin (V), chlorogenic acid (CA), hydroxybenzoic acid (HA), 3, 4-dihydroxybenzoic acid (P) and gallic acid (GA) on furfural (FF) in sugarcane juice model systems were investigated in this study. The inhibition rates of all these 5 polyphenols on the FF could reach over 90 %. The contents of Fru and 3-DG in polyphenol system were lower than those in Fru/Ser. The adducts formed from polyphenols and Fru were found in all systems and exhibited a trend of increasing first and then decreasing. The results of correlation analysis indicated CA, HA and P exerted negative effects on of FF. Polyphenols probably inhibited FF generation by 2 ways: competitive binding with the precursors and preventing the conversion of intermediates to FF by scavenging free radicals. These results provided basis for improving the quality and safety of sugarcane juice and the application of polyphenol in food industry.

摘要

本研究考察了香草醛(V)、绿原酸(CA)、羟基苯甲酸(HA)、3,4-二羟基苯甲酸(P)和没食子酸(GA)这5种多酚对甘蔗汁模型体系中糠醛(FF)的抑制机制。这5种多酚对FF的抑制率均可达90%以上。多酚体系中果糖(Fru)和3-脱氧葡萄糖(3-DG)的含量低于Fru/丝氨酸体系。在所有体系中均发现了多酚与Fru形成的加合物,且呈现先增加后降低的趋势。相关性分析结果表明,CA、HA和P对FF产生负面影响。多酚可能通过两种方式抑制FF的生成:与前体竞争性结合以及通过清除自由基阻止中间体转化为FF。这些结果为提高甘蔗汁的品质和安全性以及多酚在食品工业中的应用提供了依据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c5b/12032881/4a0cced04318/gr1.jpg

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