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γ辐射对氧化石墨烯/聚乙烯醇/银纳米线纳米复合材料性能的影响。

Effects of gamma radiation on the properties of GO/PVA/AgNW nanocomposites.

作者信息

Muradov Mustafa, Huseynov Elchin, Conradi Marjetka, Malok Matjaz, Sever Tina, Baghirov Mahammad Baghir

机构信息

Nano Research Laboratory, Baku State University 23 Academik Zahid Khalilov Street Baku AZ1148 Azerbaijan

Institute of Radiation Problems of the Ministry of Science and Education of the Republic of Azerbaijan B. Vahabzade 9 AZ 1143 Baku Azerbaijan.

出版信息

RSC Adv. 2025 Apr 28;15(17):13574-13582. doi: 10.1039/d5ra01344e. eCollection 2025 Apr 22.

Abstract

In this study, GO/PVA/AgNWs nanocomposites were exposed to gamma irradiation at doses of 8, 25, and 50 kGy to investigate the effects of gamma radiation on their structural and morphological properties. Structural modifications induced by irradiation were examined using X-ray diffraction (XRD) analysis and Raman spectroscopy, while morphological changes were evaluated through scanning electron microscopy (SEM). The findings demonstrate that gamma irradiation significantly affects the crystallinity of the nanocomposites. Although no considerable morphological alterations were observed, Raman spectroscopy confirmed the presence of radiation-induced structural defects. Analysis of the / ratio revealed that the most prominent defect formation occurred in the sample irradiated with 8 kGy, which exhibited an / ratio of 1.07. Furthermore, the study underscores the influence of gravitational forces during the composite fabrication process, as evidenced by the preferential accumulation of fillers in the lower regions of the nanocomposites. This phenomenon was validated through both XRD and SEM analyses. Overall, the study offers valuable insights into the role of gravitational effects in composite formation and elucidates the influence of low-dose gamma irradiation on the structural integrity, morphology, and optical characteristics of GO/PVA/AgNWs nanocomposites.

摘要

在本研究中,将氧化石墨烯/聚乙烯醇/银纳米线(GO/PVA/AgNWs)纳米复合材料分别置于8、25和50千戈瑞剂量的伽马辐射下,以研究伽马辐射对其结构和形态特性的影响。利用X射线衍射(XRD)分析和拉曼光谱研究辐照引起的结构变化,通过扫描电子显微镜(SEM)评估形态变化。研究结果表明,伽马辐射显著影响纳米复合材料的结晶度。虽然未观察到明显的形态改变,但拉曼光谱证实了辐射诱导结构缺陷的存在。对I_D/I_G比率的分析表明,在8千戈瑞辐照的样品中形成的缺陷最为显著,其I_D/I_G比率为1.07。此外,该研究强调了复合制备过程中重力的影响,纳米复合材料下部区域填料的优先积累证明了这一点。XRD和SEM分析均验证了这一现象。总体而言,该研究为重力效应在复合材料形成中的作用提供了有价值的见解,并阐明了低剂量伽马辐射对GO/PVA/AgNWs纳米复合材料结构完整性、形态和光学特性的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/643f/12036320/7a83ee87a1f8/d5ra01344e-f1.jpg

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