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红土土壤粉末作为用于生产高性能砂浆的胶凝材料。

Laterite soil powder as cementing material for the production of high-performance mortar.

作者信息

Yehualaw Mitiku Damtie, Nibret Hulgize, Getachew Ephrem Melaku, Endale Solomon Asrat

机构信息

Faculty of Civil and Water Resource Engineering, Bahir Dar Institute of Technology, Bahir Dar University, P.O. Box 79, Bahir Dar, Ethiopia.

School of Civil, Water Resource Engineering and Architecture, College of Engineering, Kombolcha Institute of Technology, Wollo University, Dessie, Kombolcha, Ethiopia.

出版信息

Sci Rep. 2025 May 2;15(1):15322. doi: 10.1038/s41598-025-99390-1.

Abstract

Cement has a substantial environmental impact, particularly carbon dioxide (CO) emissions, which occur mostly during the production stage, as it is anticipated that nearly 4-5% of the world's total CO emissions result from cement production. To address these environmental concerns, future scenarios will require alternative raw materials for clinker production and the usage of supplemental cementitious materials (SCMs). Hence, the current study correspondingly sought to assess the applicability of Laterite soil powder (LSP) for manufacturing High performance Mortar (HPM) and its influence on fresh, hard, and microstructure qualities with varied replacement levels. A series of experiments-including slump flow, compressive strength, chemical resistance, water absorption, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and differential thermal analysis (DTA) were conducted. The results indicate that while a superplasticizer maintained adequate flow, the addition of LSP reduced mortar flowability; for example, a 20% replacement resulted in a 23% decrease in flowability. In contrast, a 10% replacement level did not significantly affect the mechanical or durability properties over all curing periods. A one-way ANOVA (p = 0.62) confirmed that there was no statistically significant difference (p > 0.05) in compressive strength between the control mix LSP-0 and the LSP-10 mix. Furthermore, FTIR analysis indicated that a 10% LSP content exerted only a modest influence on the hydration products, as the wavenumbers, curves, peaks, and valleys observed in the spectra of the LSP-0 and LSP-10 mortar samples were nearly identical. In general, analysis of various properties indicates that a 10% LSP replacement is optimal, as it maintains performance without significant adverse effects.

摘要

水泥对环境有重大影响,尤其是二氧化碳(CO)排放,这主要发生在生产阶段,据预计,全球总CO排放量的近4-5%来自水泥生产。为解决这些环境问题,未来的方案将需要用于熟料生产的替代原材料以及补充胶凝材料(SCMs)的使用。因此,本研究相应地试图评估红土土壤粉末(LSP)用于制造高性能砂浆(HPM)的适用性及其在不同替代水平下对新拌、硬化和微观结构质量的影响。进行了一系列实验,包括坍落度流动度、抗压强度、耐化学性、吸水性、傅里叶变换红外光谱(FTIR)、热重分析(TGA)和差热分析(DTA)。结果表明,虽然高效减水剂能保持足够的流动性,但添加LSP会降低砂浆的流动性;例如,20%的替代量会导致流动性降低23%。相比之下,10%的替代水平在所有养护期内对力学性能或耐久性没有显著影响。单向方差分析(p = 0.62)证实,对照混合料LSP-0和LSP-10混合料之间的抗压强度没有统计学上的显著差异(p > 0.05)。此外,FTIR分析表明,10%的LSP含量对水化产物的影响较小,因为在LSP-0和LSP-10砂浆样品的光谱中观察到的波数、曲线、峰和谷几乎相同。总体而言,对各种性能的分析表明,10%的LSP替代是最佳的,因为它能保持性能而无明显不利影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c022/12045992/e0fabdaed5c8/41598_2025_99390_Fig1_HTML.jpg

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