Li Xingxing, Ma Ying, Shen Xiaodong, Zhong Ya, Li Yuwei
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210000, China.
Materials (Basel). 2020 Sep 24;13(19):4248. doi: 10.3390/ma13194248.
The utilization of coral waste is an economical way of using concrete in coastal and offshore constructions. Coral waste with more than 96% CaCO can be ground to fines and combined with supplementary cementitious materials (SCMs) such as fly ash, silica fume, granulated blast furnace slag in replacing Portland cement to promote the properties of cement concrete. The effects of coral sand powder (CSP) compared to limestone powder (LSP) blended with SCMs on hydration and microstructure of mortar were investigated. The result shows CSP has higher activity than LSP when participating in the chemical reaction. The chemical effect among CSP, SCMs, and ordinary Portland cement (OPC) results in the appearance of the third hydration peak, facilitating the production of carboaluminate. CSP-SCMs mortar has smaller interconnected pores on account of the porous character of CSP as well as the filler and chemical effect. The dilution effect of CSP leads to the reduction of compressive strength of OPC-CSP and OPC-CSP-SCMs mortars. The synergic effects of CSP with slag and silica fume facilitate the development of compressive strength and lead to a compacted isolation and transfer zone (ITZ) in mortar.
利用珊瑚废料是在沿海和近海建筑中使用混凝土的一种经济方式。碳酸钙含量超过96%的珊瑚废料可磨成细粉,并与粉煤灰、硅灰、粒化高炉矿渣等辅助胶凝材料(SCMs)混合,以替代波特兰水泥,改善水泥混凝土的性能。研究了与石灰石粉(LSP)相比,掺加SCMs的珊瑚砂粉(CSP)对砂浆水化和微观结构的影响。结果表明,CSP在参与化学反应时比LSP具有更高的活性。CSP、SCMs和普通波特兰水泥(OPC)之间的化学作用导致出现第三个水化峰,促进碳铝酸盐的生成。由于CSP的多孔特性以及填充和化学作用,CSP-SCMs砂浆具有较小的连通孔隙。CSP的稀释作用导致OPC-CSP和OPC-CSP-SCMs砂浆的抗压强度降低。CSP与矿渣和硅灰的协同作用促进了抗压强度的发展,并在砂浆中形成了致密的隔离和过渡区(ITZ)。