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Bubble Point Measurements of -1,1,1,4,4,4-Hexafluorobutene [R-1336mzz(Z)] + -1,2-Dichloroethene [R-1130(E)] mixtures.

作者信息

Rowane Aaron J, Outcalt Stephanie L

机构信息

Material Measurement Laboratory, Applied Chemicals and Materials Division, National Institute of Standards and Technology, 325 Broadway, Boulder, CO 80305-3337, USA.

出版信息

Int J Thermophys. 2024;45(96). doi: 10.1007/s10765-024-03388-2.

Abstract

Saturation pressures of pure R-1336mzz(Z) and R-1130(E) and bubble point pressures of three R-1336mzz(Z)/1130(E) blends were measured from 265 K to 360 K. For each pure refrigerant or refrigerant blend, a total of twenty unique saturation pressures or bubble points were measured. In total 100 unique state points were obtained. Presently, no Helmholtz-energy-explicit type equation of state (EoS) is available for R-1130(E). While an extended corresponding states EoS for R-1130(E) is available to estimate the properties of the R-1336mzz(Z)/1130(E) blend, this model does not resolve the azeotropic behavior of the mixture. Therefore, the perturbed-chain statistical-associating fluid theory (PC-SAFT) EoS is used to model the vapor-liquid equilibria of the R-1336mzz(Z)/1130(E) blend. PC-SAFT model parameters are reported, and the overall performance of the model is characterized by deviations from the experimental data.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/b03b48351cf1/nihms-2022140-f0001.jpg

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