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Bubble Point Measurements of -1,1,1,4,4,4-Hexafluorobutene [R-1336mzz(Z)] + -1,2-Dichloroethene [R-1130(E)] mixtures.

作者信息

Rowane Aaron J, Outcalt Stephanie L

机构信息

Material Measurement Laboratory, Applied Chemicals and Materials Division, National Institute of Standards and Technology, 325 Broadway, Boulder, CO 80305-3337, USA.

出版信息

Int J Thermophys. 2024;45(96). doi: 10.1007/s10765-024-03388-2.

DOI:10.1007/s10765-024-03388-2
PMID:40331081
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12053543/
Abstract

Saturation pressures of pure R-1336mzz(Z) and R-1130(E) and bubble point pressures of three R-1336mzz(Z)/1130(E) blends were measured from 265 K to 360 K. For each pure refrigerant or refrigerant blend, a total of twenty unique saturation pressures or bubble points were measured. In total 100 unique state points were obtained. Presently, no Helmholtz-energy-explicit type equation of state (EoS) is available for R-1130(E). While an extended corresponding states EoS for R-1130(E) is available to estimate the properties of the R-1336mzz(Z)/1130(E) blend, this model does not resolve the azeotropic behavior of the mixture. Therefore, the perturbed-chain statistical-associating fluid theory (PC-SAFT) EoS is used to model the vapor-liquid equilibria of the R-1336mzz(Z)/1130(E) blend. PC-SAFT model parameters are reported, and the overall performance of the model is characterized by deviations from the experimental data.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/b16b07d4f582/nihms-2022140-f0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/b03b48351cf1/nihms-2022140-f0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/0fe93ae201f9/nihms-2022140-f0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/ebe388592244/nihms-2022140-f0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/18dcb0e06fb0/nihms-2022140-f0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/b16b07d4f582/nihms-2022140-f0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/b03b48351cf1/nihms-2022140-f0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/0fe93ae201f9/nihms-2022140-f0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/ebe388592244/nihms-2022140-f0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/18dcb0e06fb0/nihms-2022140-f0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e336/12053543/b16b07d4f582/nihms-2022140-f0005.jpg

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本文引用的文献

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Bubble Point Measurements of Mixtures of HFO and HFC Refrigerants.氢氟烯烃（HFO）和氢氟碳化物（HFC）制冷剂混合物的泡点测量
J Chem Eng Data. 2021;66(12). doi: 10.1021/acs.jced.1c00654.
3
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Bubble-Point Measurements of -Propane + -Decane Binary Mixtures with Comparisons of Binary Mixture Interaction Parameters for Linear Alkanes.丙烷 + 癸烷二元混合物的泡点测量以及线性烷烃二元混合物相互作用参数的比较
J Chem Eng Data. 2016 Jul 14;61(7):2573-2579. doi: 10.1021/acs.jced.6b00258. Epub 2016 Jul 1.
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