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二水合双（4-甲基吡啶-κ）双（硫氰酸根合-κ）钴（II）的合成、晶体结构及热性质

Synthesis, crystal structure and thermal properties of di-aqua-bis-(4-methyl-pyridine-κ)bis-(thio-cyanato-κ)cobalt(II).

作者信息

Näther Christian, Boeckmann Jan

机构信息

Institut für Anorganische Chemie, Universität Kiel, Germany.

出版信息

Acta Crystallogr E Crystallogr Commun. 2025 Apr 24;81(Pt 5):420-424. doi: 10.1107/S2056989025003469. eCollection 2025 May 1.

DOI:10.1107/S2056989025003469
PMID:40336900
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12054762/
Abstract

The reaction of Co(NCS) and 4-methyl-pyridine (CHN) in water leads to the formation of light-blue single crystals of the title compound, [Co(NCS)(CHN)(HO)]. The asymmetric unit consists of one Co cation (site symmetry 1) as well as one thio-cyanate anion, one 4-methyl-pyridine coligand and one water mol-ecule in general positions to generate -CoNO octa-hedra. In the crystal, the complexes are linked by O-H⋯S hydrogen bonds into a layered network. Powder X-ray diffraction (PXRD) shows that a pure sample has been obtained. Upon heating, the title compound loses its water mol-ecules and transforms into Co(NCS)(CHN), which is already reported in the literature.

摘要

Co(NCS) 与 4-甲基吡啶 (CHN) 在水中反应生成标题化合物 [Co(NCS)(CHN)(HO)] 的浅蓝色单晶。不对称单元由一个 Co 阳离子（位点对称性 1）以及一个硫氰酸根阴离子、一个 4-甲基吡啶共配体和一个处于一般位置的水分子组成，形成 -CoNO 八面体。在晶体中，配合物通过 O-H⋯S 氢键连接成层状网络。粉末 X 射线衍射 (PXRD) 表明已获得纯样品。加热时，标题化合物失去水分子并转化为 Co(NCS)(CHN)，这在文献中已有报道。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/eb7711471dba/e-81-00420-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/01091fef6a32/e-81-00420-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/82a2947d1016/e-81-00420-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/21bb05c1da9e/e-81-00420-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/9d2567ee5bdb/e-81-00420-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/cfe5a56f1599/e-81-00420-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/eb7711471dba/e-81-00420-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/01091fef6a32/e-81-00420-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/82a2947d1016/e-81-00420-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/21bb05c1da9e/e-81-00420-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/9d2567ee5bdb/e-81-00420-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/cfe5a56f1599/e-81-00420-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d757/12054762/eb7711471dba/e-81-00420-fig6.jpg

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