Hyperspectral characterization of wastewater in the Tijuana River Estuary using laboratory, field, and EMIT satellite spectroscopy.

Hundreds of millions of liters of untreated wastewater are discharged into the Tijuana River annually, impacting communities on both sides of the US-Mexico border. Current monitoring methods are resource-intensive and limited in coverage. Optical satellite imaging may enable broader spatiotemporal monitoring, yet retrievals of bacterial concentrations and other key water quality indicators remain challenging. Here we investigate the utility of spectroscopic sensors to monitor the presence of wastewater in this estuarine-coastal system, as a proxy for bacterial concentrations and other water quality parameters. We prepared dilutions of untreated wastewater and uncontaminated seawater, measuring visible through shortwave infrared (VSWIR; 350-2500 nm) reflectance spectra of each sample. At high wastewater concentrations, a distinct spectral feature centered near 620 nm strongly correlated with paired water quality measurements (R ≥ 0.97, p-value < 0.01). This feature is additionally observed in multispectral resolution, in field observations, and in hyperspectral satellite imagery. An example application of plume mapping with this feature is presented, representing one of the earliest adoptions of EMIT hyperspectral satellite imagery for water quality monitoring. These results are promising for the use of spectroscopic sensors to map and monitor wastewater pollution in the Tijuana River Estuary and potentially, similarly polluted coastal and estuarine systems.