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孔隙结构和煤的基本性质对煤中瓦斯高效解吸能力的影响

Influence of Pore Structure and Basic Coal Properties on Gas Efficient Desorption Capacity in Coal.

作者信息

Yu Zhengfeng, Bai Jianping, Yang Jindong, Han Lei

机构信息

National Key Laboratory of Coal and CBM Co-mining, Jincheng 048012, China.

Shanxi Lanyan Coalbed Methane Engineering Research Co., Ltd, Jincheng 048012, China.

出版信息

ACS Omega. 2025 Apr 24;10(17):17504-17514. doi: 10.1021/acsomega.4c10950. eCollection 2025 May 6.

Abstract

The gas desorption capacity is beneficial for predicting and optimizing gas recovery from coalbed methane reserves. In this study, coal samples were collected from the southern Qinshui Basin. The isothermal adsorption experiment and mercury injection capillary pressure test were adopted to study the gas desorption capacity and pore structure. The efficient desorption capacity definition was proposed to evaluate the efficient desorption stage. The results show that the micropores and transition pores are well developed in all of the coal samples. There are two fractal dimensions in coal: the percolation fractal dimension (D1) and the diffusion fractal dimension (D2). A larger pore volume and well-connected pore network facilitate efficient desorption and transport of methane, leading to an enhanced methane yield. D1 is positively correlated with efficient desorption capacity, while D2 has a weaker effect. In addition, the basic properties of coal samples, such as coal rank, vitrinite content, and inertinite content, also have a certain effect on the efficient desorption capacity, but the relationship is not clear. These findings enhance our understanding of coalbed methane desorption capacity.

摘要

瓦斯解吸能力有利于预测和优化煤层气储量的瓦斯开采。在本研究中,煤样采自沁水盆地南部。采用等温吸附实验和压汞毛细管压力测试来研究瓦斯解吸能力和孔隙结构。提出了有效解吸能力的定义以评估有效解吸阶段。结果表明,所有煤样中的微孔和过渡孔发育良好。煤中有两个分形维数:渗流分形维数(D1)和扩散分形维数(D2)。较大的孔隙体积和连通性良好的孔隙网络有利于甲烷的有效解吸和运移,从而提高甲烷产量。D1与有效解吸能力呈正相关,而D2的影响较弱。此外,煤样的基本性质,如煤阶、镜质组含量和惰质组含量,对有效解吸能力也有一定影响,但关系不明确。这些发现增进了我们对煤层气解吸能力的理解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0178/12059927/5284d1699019/ao4c10950_0001.jpg

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