Cheng Ran, Wu Mingkun, Zhou Juan, Tian Mengkui
School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, P. R. China.
ACS Omega. 2025 Apr 21;10(17):17917-17928. doi: 10.1021/acsomega.5c01000. eCollection 2025 May 6.
Ceramic membrane dewatering and filtration technology is effective in reducing the water content of the phosphate slurry. However, membrane fouling remains an unavoidable issue. Herein, by investigating the mechanism of membrane contamination and developing innovative cleaning solutions, we can effectively address this issue. The main fouling form of ceramic membranes was observed to be complete blockage through analysis of the fouling process at various pollution time intervals by scanning electron microscopy (SEM) and mathematical model fitting. In addition, after cleaning severely contaminated membranes with a pollution rate of approximately 90%, a cleaning agent composed of surfactants, acid-washing agents, chelating agents, and auxiliaries was developed to address the phosphate contaminants. Owing to the combined effect of the detergent components, heavily soiled ceramic membranes can achieve a high flux recovery rate of over 90% after cleaning. This work offers new insights into ceramic membrane fouling and cleaning during phosphate slurry filtration.
陶瓷膜脱水和过滤技术在降低磷矿浆含水量方面是有效的。然而,膜污染仍然是一个不可避免的问题。在此,通过研究膜污染的机制并开发创新的清洗解决方案,我们可以有效地解决这个问题。通过扫描电子显微镜(SEM)对不同污染时间间隔的污染过程进行分析和数学模型拟合,观察到陶瓷膜的主要污染形式是完全堵塞。此外,在用污染率约为90%的严重污染膜进行清洗后,开发了一种由表面活性剂、酸洗试剂、螯合剂和助剂组成的清洗剂来处理磷污染物。由于洗涤剂成分的综合作用,严重污染的陶瓷膜在清洗后可以实现超过90%的高通量回收率。这项工作为磷矿浆过滤过程中陶瓷膜的污染和清洗提供了新的见解。