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通过Excel求解器函数评估和选择以牛骨炭为吸附剂去除铜和镍的动力学模型与等温线模型

Evaluating and Selecting Kinetic and Isotherm Models for Copper and Nickel Removal Using Cow Bone Char as an Adsorbent via Excel Solver Functions.

作者信息

Tansomros Pornmongkol, Aungthitipan Poramed, Wongcharee Surachai, Hongthong Sukanya, Kreetachat Torpong, Suriyachai Nopparat, Dechapanya Wipada, Papukdee Nipada, Jareanpon Chatklaw

机构信息

Field of Civil Engineering, Faculty of Engineering, Mahasarakham University, Khamriang, Kantarawichai, Mahasarakham 44150, Thailand.

Field of Environmental Engineering, Faculty of Engineering, Mahasarakham University, Khamriang, Kantarawichai, Mahasarakham 44150, Thailand.

出版信息

Int J Mol Sci. 2025 May 1;26(9):4316. doi: 10.3390/ijms26094316.

DOI:10.3390/ijms26094316
PMID:40362556
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12072276/
Abstract

This study explores the effectiveness of cow bone char as a low-cost, eco-friendly, and biodegradable adsorbent for removing Cu(II) and Ni(II) ions from acidic wastewater as challenging is due to heavy metal-contaminated industrial wastewater. Batch adsorption experiments were conducted to evaluate performance, with advanced nonlinear kinetic and isotherm models applied to analyze the adsorption behavior. Model fitting was performed using Microsoft Excel Solver, and model selection was validated using the Akaike Information Criterion and Average Absolute Relative Deviation Percentage. The FL-PFO kinetic model provided the best fit for time-dependent data, while the Liu and Toth isotherm models most accurately described equilibrium adsorption. Maximum adsorption capacities were 110 mg g for Cu(II) and 95 mg g for Ni(II), with Cu(II) exhibiting faster and more complete removal. Reusability testing over five cycles showed good potential for repeated use, though with gradual efficiency decline due to structural degradation and limited site regeneration. These results confirm the suitability of cow bone char as a sustainable and effective adsorbent for heavy metal removal, particularly in low-resource or decentralized water treatment systems.

摘要

本研究探讨了牛骨炭作为一种低成本、环保且可生物降解的吸附剂，用于从酸性废水中去除铜（II）和镍（II）离子的有效性，因为重金属污染的工业废水处理颇具挑战性。进行了批量吸附实验以评估其性能，并应用先进的非线性动力学和等温线模型来分析吸附行为。使用Microsoft Excel Solver进行模型拟合，并使用赤池信息准则和平均绝对相对偏差百分比对模型选择进行验证。FL-PFO动力学模型最适合时间相关数据，而Liu和Toth等温线模型最准确地描述了平衡吸附。铜（II）的最大吸附容量为110 mg/g，镍（II）为95 mg/g，铜（II）的去除速度更快且更完全。五个循环的可重复使用性测试表明其具有良好的重复使用潜力，不过由于结构降解和位点再生有限，效率会逐渐下降。这些结果证实了牛骨炭作为一种可持续且有效的重金属去除吸附剂的适用性，特别是在资源匮乏或分散式水处理系统中。

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本文引用的文献

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Materials (Basel). 2023 Jul 7;16(13):4884. doi: 10.3390/ma16134884.
2
A comprehensive review on modelling the adsorption process for heavy metal removal from waste water using artificial neural network technique.关于使用人工神经网络技术模拟从废水中去除重金属吸附过程的综合综述。
Heliyon. 2023 Apr 17;9(4):e15455. doi: 10.1016/j.heliyon.2023.e15455. eCollection 2023 Apr.
3
Value-added materials recovered from waste bone biomass: technologies and applications.
从废弃骨生物质中回收的增值材料：技术与应用
RSC Adv. 2022 Aug 10;12(34):22302-22330. doi: 10.1039/d2ra03557j. eCollection 2022 Aug 4.
4
Heavy metal-contained wastewater in China: Discharge, management and treatment.中国含重金属废水：排放、管理与处理。
Sci Total Environ. 2022 Feb 20;808:152091. doi: 10.1016/j.scitotenv.2021.152091. Epub 2021 Dec 1.
5
Ammonium thiocyanate functionalized graphene oxide-supported nanoscale zero-valent iron for adsorption and reduction of Cr(VI).硫氰酸铵功能化氧化石墨烯负载的纳米零价铁用于 Cr(VI)的吸附和还原。
J Colloid Interface Sci. 2020 Nov 15;580:345-353. doi: 10.1016/j.jcis.2020.07.016. Epub 2020 Jul 10.
6
Looking at non-sensory factors underlying consumers' perception of smoked bacon.研究消费者对熏肉感知的非感官因素。
Meat Sci. 2020 May;163:108072. doi: 10.1016/j.meatsci.2020.108072. Epub 2020 Jan 25.
7
A Review of Non-Soil Biochar Applications.非土壤生物炭应用综述
Materials (Basel). 2020 Jan 7;13(2):261. doi: 10.3390/ma13020261.
8
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J Colloid Interface Sci. 2019 Sep 1;551:195-207. doi: 10.1016/j.jcis.2019.05.007. Epub 2019 May 3.
9
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Mol Med Rep. 2017 May;15(5):3355-3360. doi: 10.3892/mmr.2017.6381. Epub 2017 Mar 24.
10
Effect of endogenous hydrolytic enzymes pretreatment on the anaerobic digestion of sludge.内源水解酶预处理对污泥厌氧消化的影响。
Bioresour Technol. 2013 Oct;146:758-761. doi: 10.1016/j.biortech.2013.07.087. Epub 2013 Jul 26.