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不同环境条件下碳纤维织物/聚醚酮酮复合材料的力学性能研究

Study on the Mechanical Properties of Carbon Fabric/Polyetherketoneketone Composites Under Different Environmental Conditions.

作者信息

Xu Xiangyu, Zhang Baoyan, Shi Fenghui, Liu Kai, Peng Gongqiu, Gao Junpeng

机构信息

AVIC Manufacturing Technology Institute Composite Technology Center, Beijing 101300, China.

School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081, China.

出版信息

Polymers (Basel). 2025 Apr 22;17(9):1142. doi: 10.3390/polym17091142.

Abstract

Carbon fabric reinforced polyetherketoneketone (CFF/PEKK) composites have garnered significant attention from researchers due to their superior properties and have been successfully applied in various engineering fields. Environmental conditions are known to directly influence the mechanical properties and service life of composites; however, limited literature exists on the mechanical behavior of CFF/PEKK composites under different environmental conditions. This study elucidates the correlation between the bending and shear behaviors of CFF/PEKK composites and environmental factors, thereby offering robust data support for engineering applications. In this work, CFF/PEKK composite laminates with a fiber volume fraction of 55 vol% were fabricated and subjected to saturated moisture absorption treatments at 70 °C. The moisture absorption characteristics of the material were investigated. The bending and shear properties of CFF/PEKK composites were characterized under three environmental conditions: -55 °C dry state (CTD), room temperature dry state (RTD), and 70 °C wet state (ETW). Failure modes and mechanisms of composite specimens were also analyzed. The equilibrium moisture absorption rate of CFF/PEKK composites is approximately 0.27%. Hygrothermal aging resulted in noticeable fiber pull-out in mechanical specimens, indicating damage to the interfacial performance of the composites. Furthermore, no cracks or delamination were observed. Results indicate that in the CTD condition, the bending strength and shear strength of CFF/PEKK composites are higher compared to those in the RTD condition, while the modulus remains relatively unaffected. In the ETW condition, both bending and shear properties exhibit a significant decline, with the most pronounced reduction observed in interlaminar shear strength. No significant differences in failure modes were noted across different environmental conditions.

摘要

碳纤维织物增强聚醚酮酮(CFF/PEKK)复合材料因其优异性能而受到研究人员的广泛关注,并已成功应用于各个工程领域。众所周知,环境条件会直接影响复合材料的力学性能和使用寿命;然而,关于CFF/PEKK复合材料在不同环境条件下力学行为的文献却很有限。本研究阐明了CFF/PEKK复合材料的弯曲和剪切行为与环境因素之间的相关性,从而为工程应用提供有力的数据支持。在这项工作中,制备了纤维体积分数为55 vol%的CFF/PEKK复合层压板,并在70℃下进行饱和吸湿处理。研究了材料的吸湿特性。在三种环境条件下对CFF/PEKK复合材料的弯曲和剪切性能进行了表征:-55℃干燥状态(CTD)、室温干燥状态(RTD)和70℃潮湿状态(ETW)。还分析了复合材料试样的失效模式和机理。CFF/PEKK复合材料的平衡吸湿率约为0.27%。湿热老化导致力学试样中出现明显的纤维拔出,表明复合材料的界面性能受到破坏。此外,未观察到裂纹或分层现象。结果表明,在CTD条件下,CFF/PEKK复合材料的弯曲强度和剪切强度高于RTD条件下的强度,而模量相对不受影响。在ETW条件下,弯曲和剪切性能均显著下降,层间剪切强度下降最为明显。在不同环境条件下,失效模式没有显著差异。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e64a/12073218/9b44c87a9a28/polymers-17-01142-g001.jpg

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