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用于柔性电子学潜在应用的PVA/Cu纳米复合材料的增强结构、光学、电学和介电性能

Enhanced Structural, Optical, Electrical, and Dielectric Properties of PVA/Cu Nanocomposites for Potential Applications in Flexible Electronics.

作者信息

Hernández Marco A Alaniz, Ascencio Hurtado Carlos, Garcia Filiberto Candia, Lázaro Roberto C Ambrosio, Ortega Manuel A Chairez, Arriaga Cesar A Arriaga, Castillo Amanda Carrillo

机构信息

Manufacturing Department, Ciudad Juarez Autonomous University, Chihuahua 32310, Mexico.

Electronic Department, Meritorious Autonomous University of Puebla, Puebla 72590, Mexico.

出版信息

Materials (Basel). 2025 May 2;18(9):2087. doi: 10.3390/ma18092087.

Abstract

Copper (Cu) nanoparticles, known for their high electrical conductivity and cost-effectiveness, have emerged as essential materials in various applications from flexible electronics to antimicrobial agents. This work focuses on the synthesis and characterization of semiconductive nanostructured films composed of polyvinyl alcohol (PVA) with embedded Cu nanoparticles. The study provides a comprehensive analysis of the structural, optical, electrical, and dielectric properties of the resulting nanocomposites. The results indicate a significant reduction in optical band gap, from 4.82 eV in pure PVA to 2.6-2.8 eV in the nanocomposites, alongside enhanced electrical conductivities reaching 1.20 S/cm for films with 5 wt.% Cu. Dielectric assessments further reveal high dielectric constants, underscoring the potential of these materials for flexible electronic applications. This work highlights the effectiveness of incorporating Cu nanoparticles into polymer matrices, paving the way for advanced materials that meet the demands of next-generation electronics.

摘要

铜(Cu)纳米颗粒以其高导电性和成本效益而闻名,已成为从柔性电子到抗菌剂等各种应用中的重要材料。这项工作专注于由嵌入铜纳米颗粒的聚乙烯醇(PVA)组成的半导体纳米结构薄膜的合成与表征。该研究对所得纳米复合材料的结构、光学、电学和介电性能进行了全面分析。结果表明,光学带隙显著降低,从纯PVA中的4.82电子伏特降至纳米复合材料中的2.6 - 2.8电子伏特,同时对于含5重量%铜的薄膜,电导率提高到1.20 S/cm。介电评估进一步揭示了高介电常数,突出了这些材料在柔性电子应用中的潜力。这项工作突出了将铜纳米颗粒掺入聚合物基质的有效性,为满足下一代电子需求的先进材料铺平了道路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e245/12072678/f193d9c39e1c/materials-18-02087-g001.jpg

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