Guo Yuliang, Cao Liwen, Zhang Rui, Chen Weiwei, Chen Haobo
Jiangsu Key Laboratory of Coal Based Greenhouse Gas Control and Utilization, China University of Mining and Technology, Xuzhou, 221008, China.
Carbon Neutrality Institute, China University of Mining and Technology, Xuzhou, 221008, China.
Sci Rep. 2025 May 17;15(1):17204. doi: 10.1038/s41598-025-02498-7.
The degradation of organic contaminants from domestic sources can lead to a reduction in soil strength and the emission of greenhouse gases such as methane (CH) and carbon dioxide (CO). It is crucial to explore green and low-carbon disposal methods for domestic-sources-contaminated soil. In this study, biochar was utilized to remediate domestic-sources-contaminated soil due to its stable performance and excellent adsorption and fixation of organic matter. The geotechnical tests and thermogravimetric analysis were investigated to evaluate the remediation effects of biochar dosage and particle size from environmental and engineering viewpoints. The results identified clear and effective ranges for biochar dosage and particle size in remediation of domestic-sources-contaminated soil, and biochar can simultaneously achieve environmental and engineering remediation. The optimal remediation effect was observed with a biochar dosage of 6% and a particle size of 1-3 mm. The remediation mechanisms of biochar on domestic-sources-contaminated soil primarily consisted of adsorption and aggregation, regulation of physicochemical properties, and alteration of structural. At lower biochar dosages and smaller particle sizes, adsorption and aggregation and regulation of physicochemical properties were dominant, while at higher dosages and larger particle sizes, alteration of structural became the main factor. This study preliminarily confirmed the feasibility of biochar in the synergistic environmental and engineering remediation of domestic-sources-contaminated soil, providing a basis for the development of coupling technology for carbon sequestration and remediation with biochar of such soil.
来自生活源的有机污染物降解会导致土壤强度降低,并排放甲烷(CH)和二氧化碳(CO)等温室气体。探索针对生活源污染土壤的绿色低碳处置方法至关重要。在本研究中,生物炭因其性能稳定且对有机物具有优异的吸附和固定能力而被用于修复生活源污染土壤。从环境和工程角度研究了土工试验和热重分析,以评估生物炭用量和粒径的修复效果。结果确定了生物炭用量和粒径在修复生活源污染土壤中的明确有效范围,生物炭可同时实现环境和工程修复。生物炭用量为6%、粒径为1 - 3毫米时观察到最佳修复效果。生物炭对生活源污染土壤的修复机制主要包括吸附与团聚、物理化学性质调控以及结构改变。在较低生物炭用量和较小粒径时,吸附与团聚以及物理化学性质调控起主导作用,而在较高用量和较大粒径时,结构改变成为主要因素。本研究初步证实了生物炭在生活源污染土壤协同环境与工程修复中的可行性,为开发利用生物炭进行此类土壤固碳与修复的耦合技术提供了依据。