Advances and future perspectives on silicon-based anodes for lithium-ion batteries.

Silicon (Si)-based anode has emerged as the most promising anode material for next-generation lithium-ion batteries (LIBs) due to its high specific capacity, suitable operating potential and abundant natural reserves. Nevertheless, the drastic volume effect of Si particles during lithiation/delithiation leads to particle pulverization, electrode structure collapse, and solid electrolyte interfacial (SEI) film instability, which results in a rapid reversible capacity degradation of Si-based anodes. It is essential to deeply analyze the failure mechanism of silicon-based electrodes and explore suitable improvement methods to achieve higher capacity retention. Herein, we systematically summarize the improvement strategies for Si-based anodes, including regulating material particle size, optimizing structure and composition, and exploring new binders, along with their enhancement mechanisms. In addition, the preparation of high-performance Si-based electrodes based on newly developed 3D printing technology in recent years is discussed. Lastly, several possible directions and emerging challenges for Si anode are presented to facilitate further improvement in practical applications. Overall, this review is expected to provide basic understanding and insights into the practical application of Si-based materials in next-generation LIBs negative electrodes.