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鱿鱼中氧化三甲胺向三甲胺和二甲胺的热转化

Thermal conversion of trimethylamine-N-oxide to trimethylamine and dimethylamine in squids.

作者信息

Lin J K, Hurng D C

出版信息

Food Chem Toxicol. 1985 Jun;23(6):579-83. doi: 10.1016/0278-6915(85)90182-6.

DOI:10.1016/0278-6915(85)90182-6
PMID:4040104
Abstract

The levels of dimethylamine-nitrogen (DMA-N), trimethylamine-nitrogen (TMA-N) and trimethylamine-N-oxide-nitrogen (TMAO-N) were determined in five species of dried squid. Each sample contained extremely high levels of TMAO-N (2558-8064 ppm) and moderate amounts of TMA-N (121-503 ppm) and DMA-N (124-373 ppm). Over 90% of TMAO-N in squid was converted to TMA-N and DMA-N after heating at 200 degrees C for 1 hr; approximately 50% of the volatile TMA-N and DMA-N was lost during the course of the heating. The thermal conversions were accelerated by heat, and possibly involved catalysis by certain tissue constituents. Squids are a popular seafood in most oriental countries, but before appearing on the market they are subjected to a long food-processing procedure. Therefore, a high concentration of TMAO in squids is an important problem, for food technology as well as toxicology.

摘要

测定了五种鱿鱼干中二甲胺氮(DMA-N)、三甲胺氮(TMA-N)和氧化三甲胺氮(TMAO-N)的含量。每个样品中TMAO-N含量极高(2558 - 8064 ppm),TMA-N含量适中(121 - 503 ppm),DMA-N含量适中(124 - 373 ppm)。鱿鱼中超过90%的TMAO-N在200℃加热1小时后转化为TMA-N和DMA-N;在加热过程中,约50%的挥发性TMA-N和DMA-N损失。热转化受热加速,可能涉及某些组织成分的催化作用。鱿鱼在大多数东方国家是一种受欢迎的海鲜,但在上市之前要经过漫长的食品加工过程。因此,鱿鱼中高浓度的TMAO对食品技术和毒理学来说都是一个重要问题。

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