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将入侵性杂草转化为能源解决方案:用于绿色超级电容器的基于水葫芦的混合电极。

Transforming invasive weeds into energy solutions: water hyacinth-based hybrid electrodes for green supercapacitors.

作者信息

Simon Shilpa, Cherian Anila Rose, B Sreeja P

机构信息

Department of Chemistry, CHRIST University Bengaluru 560029 India

出版信息

RSC Adv. 2025 May 23;15(22):17302-17316. doi: 10.1039/d5ra02140e. eCollection 2025 May 21.

Abstract

The excessive proliferation of (water hyacinth) poses significant environmental challenges; however, its abundant biomass offers a sustainable solution for energy storage applications. This study presents an eco-friendly approach to fabricating high-performance supercapacitor electrodes using water hyacinth-derived activated carbon (WH), polypyrrole (PPy), and titanium dioxide (TiO). The WH-TiO/PPy hybrid electrode was synthesized hydrothermal treatment and interfacial polymerization, ensuring a resource-efficient and environmentally responsible process. The composite exhibited a high gravimetric capacitance of 610 F g at 0.5 A g in 3 M KOH, with excellent cycling stability (94% retention after 5000 cycles). An asymmetric supercapacitor with WH-TiO/PPy as the positive electrode and activated carbon as the negative electrode delivered an energy density of 98 W h kg and a power density of 5606 W kg. This work highlights the potential of transforming invasive biomass into cost-effective, high-performance energy storage materials, advancing the principles of green chemistry through waste valorization and sustainable material design.

摘要

凤眼蓝的过度繁殖带来了重大的环境挑战;然而,其丰富的生物质为能量存储应用提供了一种可持续的解决方案。本研究提出了一种生态友好的方法,使用凤眼蓝衍生的活性炭(WH)、聚吡咯(PPy)和二氧化钛(TiO)来制造高性能超级电容器电极。通过水热处理和界面聚合合成了WH-TiO/PPy混合电极,确保了资源高效和环境友好的过程。该复合材料在3 M KOH中,在0.5 A g时表现出610 F g的高比电容,具有出色的循环稳定性(5000次循环后保留94%)。以WH-TiO/PPy为正极、活性炭为负极的不对称超级电容器的能量密度为98 W h kg,功率密度为5606 W kg。这项工作突出了将入侵性生物质转化为具有成本效益的高性能储能材料的潜力,通过废物 valorization和可持续材料设计推进绿色化学原则。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c7b/12099493/d7a85af6f347/d5ra02140e-f1.jpg

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