[(TMEDA)Li(μ-PPh)K(TMEDA)(THF)]: a heterobimetallic molecular lithium-potassium phosphide complex.

作者信息

Crabbe Michelle H, O'Meara Danielle, Kennedy Alan R, Weetman Catherine E, Mulvey Robert E

机构信息

Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, G1 1XL, UK.

出版信息

Chem Commun (Camb). 2025 Jun 24;61(52):9436-9439. doi: 10.1039/d5cc02154e.

Made by a co-complexation reaction, heterobimetallic [(TMEDA)Li(μ-PPh)K(TMEDA)(THF)] has been crystallographically and spectroscopically characterised, modelled by DFT calculations, and its performance compared against those of its homometallic phosphide components in preliminary studies of its application in catalytic hydrophosphination reactions of a representative alkene.