Mojapelo Kobe Samuel, Kupolati Williams Kehinde, Burger Everardt Andre, Ndambuki Julius Musyoka, Snyman Jacques, Sadiku Emmanuel Rotimi, Ibrahim Idowu David
Department of Civil Engineering, Tshwane University of Technology, Pretoria, South Africa.
Institute for NanoEngineering Research (INER), Department of Chemical Metallurgy and Materials Engineering, Tshwane University of Technology, Pretoria, South Africa.
Sci Rep. 2025 May 29;15(1):18956. doi: 10.1038/s41598-025-04151-9.
This study investigated the potential of wastewater sludge (WWS) as a partial replacement for fine aggregates in non-structural concrete to optimise its mechanical properties while mitigating environmental impacts. WWS from three wastewater treatment plants (WWTPs), Mankweng, Polokwane, and Seshego, in Limpopo Province, South Africa, was used to replace sand at 0, 5, 10, 15, and 20% by weight. Scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), and energy-dispersive X-ray analysis (EDX) were used to characterise the organic compositions of the sludge and sludge-based concrete. The environmental safety of the sludge-based concrete was then assessed through the Toxicity Characteristic Leaching Procedure (TCLP) at 28, 90, and 140 days, ensuring compliance with heavy metal leaching limits. The results demonstrate that at a 5% replacement level, the concrete maintained an average compressive strength of 25 MPa after 90 days, meeting general construction standards for non-structural and low load-bearing applications. The incorporation of wastewater sludge had low leachable heavy metals, with TCLP results confirming all tested metals remained below regulatory limits throughout. However, increasing WWS content beyond 10% resulted in higher porosity, reduced compressive strength, and increased water absorption, which compromise durability. The findings highlight the importance of optimising replacement levels and mix design to balance sustainability, mechanical performance, and regulatory compliance.
本研究调查了废水污泥(WWS)作为非结构混凝土中细集料的部分替代品的潜力,以优化其力学性能,同时减轻环境影响。使用了来自南非林波波省曼克翁、波罗克瓦尼和塞舍戈三个污水处理厂(WWTPs)的废水污泥,以重量百分比0、5、10、15和20%替代沙子。采用扫描电子显微镜(SEM)、X射线衍射分析(XRD)和能量色散X射线分析(EDX)对污泥和基于污泥的混凝土的有机成分进行表征。然后通过毒性特征浸出程序(TCLP)在28、90和140天评估基于污泥的混凝土的环境安全性,确保符合重金属浸出限值。结果表明,在5%的替代水平下,混凝土在90天后保持平均抗压强度25MPa,符合非结构和低承载应用的一般施工标准。废水污泥的掺入导致可浸出重金属含量较低,TCLP结果证实所有测试金属始终低于监管限值。然而,当WWS含量超过10%时,孔隙率增加、抗压强度降低且吸水率增加,这会损害耐久性。研究结果强调了优化替代水平和配合比设计以平衡可持续性、力学性能和法规合规性的重要性。