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低温条件下自膨胀聚合物灌浆材料发泡特性及微观结构的试验研究

Experimental study on foaming characteristics and microstructure of self-expanding polymer grouting material under low-temperature conditions.

作者信息

Li Songtao, Wang Baolin, Gao Yanlong

机构信息

College of railway engineering, Zhengzhou Railway Vocational & Technical College, Zhengzhou, China.

School of Water Conservancy and Transportation, Zhengzhou University, Zhengzhou, China.

出版信息

PLoS One. 2025 Jun 4;20(6):e0311898. doi: 10.1371/journal.pone.0311898. eCollection 2025.

Abstract

Polymer grouting materials, due to their self expansion properties, have been widely used in repair engineering involving hydraulic structures and have become a new type of building material. The foaming characteristics of polymer grouting materials under low-temperature conditions directly influence their repair effectiveness in cold areas. In this study, a grouting test of the free expansion of the polymer grouting material in the vertical direction and a mold grouting test with all four sides constrained were performed under different low-temperature conditions. The structure and morphology of foam cells under different low-temperature conditions were examined via scanning electron microscopy. The test results indicated that as the temperature decreased, the volume of the foam gradually exhibited a cold shrinkage effect, and the surface temperature gradually decreased. For every 1°C decrease in temperature, the foaming volume decreases by an average of 40 cm3, and the surface temperature decreases by an average of 1.7°C. According to the foaming rate, the foaming process was divided into three stages: fast, slow, and stable foaming. Additionally, the internal temperature stress generated during the foaming process was a key factor that caused the foam to bulge outward. Under the condition where all four sides were constrained, the density of the foam formed gradually decreased as the temperature decreased. The foam cell was spherical. As the temperature decreased, the cell morphology became blurred, and the number of incomplete cell structures between the gaps increased. The research results will provide a reference for the polymer repair projects of hydraulic structures in cold regions.

摘要

聚合物灌浆材料因其自身的膨胀特性,已广泛应用于水工建筑物修复工程中,成为一种新型建筑材料。聚合物灌浆材料在低温条件下的发泡特性直接影响其在寒冷地区的修复效果。本研究在不同低温条件下进行了聚合物灌浆材料在垂直方向的自由膨胀灌浆试验以及四边约束的模具灌浆试验。通过扫描电子显微镜观察了不同低温条件下泡沫孔的结构和形态。试验结果表明,随着温度降低,泡沫体积逐渐呈现冷缩效应,表面温度逐渐下降。温度每降低1°C,发泡体积平均减少40 cm³,表面温度平均下降1.7°C。根据发泡速率,发泡过程分为快速、慢速和稳定发泡三个阶段。此外,发泡过程中产生的内部温度应力是导致泡沫向外鼓起的关键因素。在四边约束条件下,随着温度降低,形成的泡沫密度逐渐减小。泡沫孔呈球形。随着温度降低,泡孔形态变得模糊,间隙间不完全泡孔结构的数量增加。研究结果将为寒冷地区水工建筑物的聚合物修复工程提供参考。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fd43/12142650/4e2144a7acf7/pone.0311898.g001.jpg

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