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改性玉米秸秆联合超声调理对污泥脱水性能的影响

Effect of modified corn stalk combined with ultrasonic conditioning on sludge dewatering performance.

作者信息

Lin Feng, Zhang Siqi, Ma Jing, Zhang Shuxin, Wang Baoyu, Yang Huanlei

机构信息

School of Chemical Engineering and Technology, Guangdong Industry Polytechnic University Guangzhou China.

Automotive Engineering Department, Jining Polytechnic Jining China

出版信息

RSC Adv. 2025 Jun 4;15(23):18742-18751. doi: 10.1039/d5ra01085c. eCollection 2025 May 29.

Abstract

To address the challenge of high moisture content and difficulty in water removal in sludge, this study optimized the preparation conditions of modified corn stalk powder (MCSP) using solid waste corn stalk powder (CSP) as the raw material. The optimization was achieved through an alkalization-etherification process combined with response surface methodology (RSM). When the optimized MCSP was applied in combination with ultrasonic conditioning for sludge treatment, it was found that the optimal dosage of MCSP was 0.1 g g DS. At this dosage, the water content of the dewatered sludge and specific resistance to filtration (SRF) reached their lowest values, which were 1.23 × 10 m kg and 53.5%, respectively. Furthermore, the bound water content decreased from 8.53 g g DS to 4.64 g g DS. There was an increasing trend in the protein and polysaccharide contents across all extracellular polymeric substances (EPS) fractions, with the protein content in soluble EPS (S-EPS) increasing from 4.87 mg g to 21.31 mg g. At the optimal dosage, the sludge particle size increased to 98.5 μm, and the absolute value of the sludge zeta potential approached zero. The outer boundaries of the flocs became smoother, and the floc structure became more compact, resulting in optimal sludge dewatering performance. Further data analysis revealed that EPS and one-dimensional fractal dimension were the primary factors influencing sludge dewatering performance.

摘要

为应对污泥中高含水量和脱水困难的挑战,本研究以固体废物玉米秸秆粉(CSP)为原料,优化了改性玉米秸秆粉(MCSP)的制备条件。通过碱化-醚化工艺结合响应面法(RSM)实现了优化。当将优化后的MCSP与超声调理联合应用于污泥处理时,发现MCSP的最佳投加量为0.1 g g DS。在此投加量下,脱水污泥的含水量和比阻(SRF)达到最低值,分别为1.23×10 m kg和53.5%。此外,结合水含量从8.53 g g DS降至4.64 g g DS。所有胞外聚合物(EPS)组分中的蛋白质和多糖含量均呈上升趋势,可溶性EPS(S-EPS)中的蛋白质含量从4.87 mg g增至21.31 mg g。在最佳投加量下,污泥粒径增至98.5 μm,污泥zeta电位绝对值接近零。絮体的外边界变得更光滑,絮体结构变得更紧凑,从而实现了最佳的污泥脱水性能。进一步的数据分析表明,EPS和一维分形维数是影响污泥脱水性能的主要因素。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aca5/12134897/222cc464c72e/d5ra01085c-f1.jpg

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