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费萨拉巴德马德胡阿纳排水渠沿线地下水重金属污染的时空评估:源解析与健康风险分析

Spatio-temporal assessment of heavy metal contamination in groundwater along Madhuana drain, Faisalabad: source apportionment and health risk analysis.

作者信息

Bashir Muhammad Hassan, Asif Abubakar, Ahmad Hamaad Raza, Abbas Asad, Shehzad Muhammad Tahir

机构信息

Institute of Soil and Environmental Sciences, University of Agriculture, Faisalabad, 38040, Pakistan.

出版信息

Environ Geochem Health. 2025 Jun 6;47(7):251. doi: 10.1007/s10653-025-02563-0.

Abstract

Trace metals are among the most critical pollutants in wastewater, contributing to severe groundwater contamination, particularly near wastewater canals. Study novelty is that seasonal variations of groundwater metals and their associated sources through the Positive Matrix Factorization Model, with health risks through skin exposure, have not been well understood in Faisalabad along wastewater drains. This study investigates groundwater quality in the Madhuana drain and its sub-drains (Satiana and Khanuana) by examining chemical parameters, water quality indices, and trace metal concentrations (Cd, Cr, Cu, Mn, Ni, Pb, and Zn) in samples collected during the summer (n = 21) and winter (n = 21) seasons of 2023-2024. The heavy metals primary sources were anthropogenic, such as industrial effluent discharge, household waste, and agricultural runoff. Based on seasonal results, physico-chemical, biological parameters and trace metals concentrations were higher in the winter than summer season, and these parameters exceeded permissible limits of national and international guidelines. Spatial contamination follows a pattern: Satiana drain (high contamination), Madhuana drain (medium contamination), and Khanuana drain (low contamination). Satiana, Madhuana, and Khanuana drains groundwater quality have been classified as "very poor", "poor", and "slightly poor", respectively, making the water unsuitable for human intake. Health risk analyses reveal low non-carcinogenic risks (HQ < 1) from ingesting and dermal exposure, with children at higher risk than adults. During both seasons, the carcinogenic risk for Cd, Cr, Ni, and Pb was under acceptable ranges (TCR < 1). The research is based on a one-year data set, which may not have captured long-term trends, and it is limited to heavy metal contamination, not including organic and microbial contaminants. Future studies with wider monitoring as well as detailed pollutant analysis will be required. For ensuring drinking water safety, regular monitoring and remedial measures must be adopted.

摘要

痕量金属是废水中最关键的污染物之一,会导致严重的地下水污染,尤其是在废水渠附近。研究的新颖之处在于,费萨拉巴德沿废水排放口,通过正定矩阵因子分解模型对地下水金属的季节变化及其相关来源以及皮肤接触带来的健康风险尚未得到充分了解。本研究通过检测2023 - 2024年夏季(n = 21)和冬季(n = 21)采集的样本中的化学参数、水质指标和痕量金属浓度(镉、铬、铜、锰、镍、铅和锌),调查了马杜阿纳排水渠及其子排水渠(萨蒂亚纳和卡努阿纳)的地下水质量。重金属的主要来源是人为因素,如工业废水排放、家庭垃圾和农业径流。根据季节结果,冬季的物理化学、生物参数和痕量金属浓度高于夏季,且这些参数超过了国家和国际准则的允许限值。空间污染呈现出一种模式:萨蒂亚纳排水渠(高污染)、马杜阿纳排水渠(中等污染)和卡努阿纳排水渠(低污染)。萨蒂亚纳、马杜阿纳和卡努阿纳排水渠的地下水质量分别被归类为“极差”、“差”和“稍差”,这使得这些水不适合人类饮用。健康风险分析表明,摄入和皮肤接触带来的非致癌风险较低(危害商<1),儿童的风险高于成人。在两个季节中,镉、铬、镍和铅的致癌风险都在可接受范围内(总致癌风险<1)。该研究基于一年的数据集,可能未捕捉到长期趋势,并且仅限于重金属污染,不包括有机和微生物污染物。未来需要进行更广泛监测以及详细污染物分析的研究。为确保饮用水安全,必须采取定期监测和补救措施。

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