Hashami Muhammad, Ongarbayev Yerdos, Tileuberdi Yerbol, Imanbayev Yerzhan, Zhambolova Ainur, Kenzhegaliyeva Aliya, Mansurov Zulkhair
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Ave., Almaty 050040, Kazakhstan.
Department of Chemistry, Faculty of Education, Institute of Higher Education Mirwais Khan Nika Zabul, Qalat 4001, Afghanistan.
Nanomaterials (Basel). 2025 May 31;15(11):842. doi: 10.3390/nano15110842.
Carbon-based nanomaterials have emerged as a promising strategy for bitumen modification to enhance the mechanical and thermal performance of pavements. This review evaluates the present advancements in the inclusion of coke and carbon nanomaterials (CNMs) such as carbon nanotubes (CNTs) and graphene into bituminous systems. The findings and limitations of recent experiments in synthesis procedures along with dispersion methods are deeply explored to determine their impact on the rheological properties of bitumen as well as aging resistance and durability characteristics. Petroleum coke enhances bitumen softening points by 10-15 °C and causes up to 30% improvement in rutting resistance while simultaneously prolonging material fatigue life and aging resistance. Bitumen modification through petroleum coke faces challenges in addition to mixing difficulties due to its high viscosity. Moreover, the incorporation of CNTs and graphene as CNMs shows significant enhancements in rutting resistance with improved tensile strength, lower additive requirements, and enhanced dispersion. Both the superior mechanical properties of carbon nanomaterials and processing advancements in nano-enhanced bitumen have the capability to solve technical issues including material costs and specialized mixing processes. Combining coke with CNMs to enhance performance is a future research direction, which could result in economic and scalability considerations. This review comprehensively explores insights into physicochemical interactions, performance outcomes, and processing techniques, crucial for the development of sustainable, high-performance bitumen composites tailored for next-generation infrastructure applications.
碳基纳米材料已成为一种很有前景的沥青改性策略,用于提高路面的机械性能和热性能。本综述评估了将焦炭和碳纳米材料(如碳纳米管(CNT)和石墨烯)纳入沥青体系的当前进展。深入探讨了合成过程以及分散方法中近期实验的结果和局限性,以确定它们对沥青流变性能以及抗老化性和耐久性特征的影响。石油焦可使沥青软化点提高10 - 15°C,并使抗车辙性能提高多达30%,同时延长材料疲劳寿命和抗老化性。通过石油焦改性沥青除了因其高粘度导致混合困难外,还面临其他挑战。此外,将碳纳米管和石墨烯作为碳纳米材料加入,在抗车辙性能方面有显著提高,同时拉伸强度提高、添加剂需求降低且分散性增强。碳纳米材料卓越的机械性能以及纳米增强沥青的加工进展都有能力解决包括材料成本和特殊混合工艺在内的技术问题。将焦炭与碳纳米材料结合以提高性能是未来的研究方向,这可能涉及经济和可扩展性方面的考虑。本综述全面探讨了对物理化学相互作用、性能结果和加工技术的见解,这些对于开发适用于下一代基础设施应用的可持续、高性能沥青复合材料至关重要。
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