Duan Zhenjing, Wang Ziheng, Jia Yishuai, Wang Shuaishuai, Bian Peng, Tan Ji, Song Jinlong, Liu Xin
State Key Laboratory of High-Performance Precision Manufacturing, Dalian University of Technology, Dalian 116024, China.
Nanomaterials (Basel). 2025 Jun 5;15(11):874. doi: 10.3390/nano15110874.
h-BN spherical nanoparticles, known as white graphene, have good anti-wear properties, long service life, chemical inertness, and stability, which provide superior lubricating performance as a solid additive item to nanofluids. However, the poor dispersion stability of h-BN nanoparticles in nanofluids is a bottleneck that restricts their application. Currently, to prepare h-BN nanofluids with good dispersion stability, a cold plasma (CP) modification of h-BN nanoparticles is proposed in this study. In this research, h-BN nanofluid with added surfactant (SNL), CP-modified h-BN nanofluid with N as the working gas (CP(N)NL), and CP-modified h-BN nanofluid with O as the working gas (CP(O)NL) were prepared, separately. The mechanism of the dispersion stability of CP-modified h-BN nanofluid was analyzed using X-ray photoelectron spectroscopy (XPS), and the performance of CP-modified nanofluid was analyzed based on static observation of nanofluid, kinematic viscosity, and heat transfer properties. Finally, friction and wear experiments were conducted to further analyze the tribological performance of h-BN nanofluids based on the coefficient of friction, 3D surface morphology, surface roughness (Sa), scratches, and micro-morphology. The results show that CP-modified h-BN nanofluid has excellent dispersed suspension stability and can be statically placed for more than 336 h. The CP-modified h-BN nanofluid showed stable friction-reducing, anti-wear, and heat transfer performance, in which the coefficient of friction of h-BN nanofluid was about 0.66 before and after 24 h of settling. The Sa value of the sample was reduced by 31.6-49.2% in comparison with pure cottonseed oil (CO).
六方氮化硼(h-BN)球形纳米颗粒,即所谓的白色石墨烯,具有良好的抗磨损性能、长使用寿命、化学惰性和稳定性,作为纳米流体的固体添加剂具有卓越的润滑性能。然而,h-BN纳米颗粒在纳米流体中的分散稳定性较差,这是限制其应用的一个瓶颈。目前,为制备具有良好分散稳定性的h-BN纳米流体,本研究提出对h-BN纳米颗粒进行冷等离子体(CP)改性。在本研究中,分别制备了添加表面活性剂的h-BN纳米流体(SNL)、以氮气作为工作气体的CP改性h-BN纳米流体(CP(N)NL)以及以氧气作为工作气体的CP改性h-BN纳米流体(CP(O)NL)。利用X射线光电子能谱(XPS)分析了CP改性h-BN纳米流体的分散稳定性机理,并基于对纳米流体的静态观察、运动粘度和传热性能分析了CP改性纳米流体的性能。最后,进行了摩擦磨损实验,基于摩擦系数、三维表面形貌、表面粗糙度(Sa)、划痕和微观形貌进一步分析了h-BN纳米流体的摩擦学性能。结果表明,CP改性h-BN纳米流体具有优异的分散悬浮稳定性,可静态放置超过336小时。CP改性h-BN纳米流体表现出稳定的减摩、抗磨和传热性能,其中h-BN纳米流体在沉降24小时前后的摩擦系数约为0.66。与纯棉籽油(CO)相比,样品的Sa值降低了31.6 - 49.2%。