Yadav Chandradip Kumar, Yadav Brahamdeo, Shahi Neelam, Niraula Tulasi Prasad, Chaudhary Yogesh, Adhikari Manoj, Kunwar Jyotendra, Neupane Shova, Yadav Amar Prasad, Bhattarai Ajaya, Kumar Dileep
Central Department of Chemistry, Tribhuvan University, Kirtipur, Nepal.
Amrit Science Campus, Tribhuvan University, Thamel, Kathmandu, Nepal.
R Soc Open Sci. 2025 Jun 11;12(6):250015. doi: 10.1098/rsos.250015. eCollection 2025 Jun.
The effectiveness of sodium dodecyl sulfate (SDS) is investigated as an inhibitor against a 0.5 M HSO solution on mild steel (MS). The method was conducted for the calculation of critical micelle concentration (CMC) calculation, weight loss and potentiodynamic polarization. The SDS-coated steel samples were characterized by field emission scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray energy dispersive spectroscopy and atomic force microscopy to understand the surface morphologies after exposure to the CMC of SDS solution. Conductivity measurements were performed to determine the CMC of the SDS solution. It appears that SDS is a perfect inhibitor of MS corrosion, as the weight loss measurement result found an inhibition efficiency of SDS of approximately 98.37% in 0.5 M HSO solution. We also found, from the Tafel plot, a corrosion current of 0.98 × 10 A cm at CMC (0.0077 M), when MS was dipped for 9 h in 0.5 M HSO. SDS enhances the corrosion resistance of MS in acidic environments and its potential implications for industrial applications. It varies with SDS concentrations, which is attributed to the development of a protective Fe-SDS complex on the MS surface.
研究了十二烷基硫酸钠(SDS)作为一种缓蚀剂对低碳钢(MS)在0.5 M硫酸溶液中的缓蚀效果。该方法用于临界胶束浓度(CMC)计算、失重和动电位极化的测定。对涂有SDS的钢样品进行了场发射扫描电子显微镜、傅里叶变换红外光谱、X射线能量色散光谱和原子力显微镜表征,以了解暴露于SDS溶液的CMC后表面形态。进行电导率测量以确定SDS溶液的CMC。结果表明,SDS是MS腐蚀的理想缓蚀剂,因为失重测量结果发现SDS在0.5 M硫酸溶液中的缓蚀效率约为98.37%。我们还从塔菲尔曲线发现,当MS在0.5 M硫酸中浸泡9小时时,在CMC(0.0077 M)下的腐蚀电流为0.98×10 A/cm²。SDS提高了MS在酸性环境中的耐腐蚀性及其在工业应用中的潜在意义。它随SDS浓度而变化,这归因于在MS表面形成了保护性的Fe-SDS络合物。