Co-Intercalation of Sericite by Cationic and Anionic Surfactants and the Mechanical Properties of Sericite/Epoxy Resin Composites.

Although the intercalation of sericite with cationic surfactants has been extensively studied, successful intercalation using anionic surfactants has yet to be achieved. This article aims to partially or fully intercalate sericite with an anionic surfactant, and to develop the corresponding sericite/polymer nanocomposite. To achieve this goal, we modified raw sericite by thermal modification, acid activation, and sodium modification. The modified sericite was then co-intercalated by cationic surfactant hexadecyl trimethyl ammonium bromide (CTAB) and anionic surfactant sodium dodecyl sulfate (SDS). The intercalated sericite was characterized by XRD, FTIR, SEM, DTA-TG, and a contact angle tester. The optimized sample had a layer-to-layer distance of 6.56 nm and an intercalation rate of 95.7%. Compared with raw sericite, the new organo-sericite showed increased hydrophobicity. A proposed mechanism for the intercalation by these surfactants was also discussed. Finally, sericite/epoxy composite was prepared by using the new organo-sericite as the raw material, demonstrating significantly improved mechanical properties compared to pure epoxy resin (72% improved for bending strength and 62% improved for tensile strength, compared with pure epoxy resin). The new organo-sericite is a promising filler in epoxy resin to enhance thermal stability and mechanical performance of the composite.