Xu Yanling, Tian Bo, Zhu Hongzhou, Wang Junxin
School of Construction Engineering, Chongqing City Vocational College, Chongqing 402160, China.
School of Civil Engineering, Chongqing Jiaotong University, Chongqing 400074, China.
Materials (Basel). 2025 May 27;18(11):2527. doi: 10.3390/ma18112527.
Intense ultraviolet (UV) radiation is often accompanied by large temperature differences in high-altitude cold regions. Therefore, investigating the aging behavior of SBR asphalt under intense UV radiation and large temperature differences is crucial for prolonging the lifespan and maintenance of styrene-butadiene rubber (SBR)-modified asphalt pavements in high-altitude cold regions. This study investigated the aging process of SBR-modified asphalt by analyzing the chemical components, microstructures, and micromechanics of both base and SBR-modified asphalt under combined effects. Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), gel permeation chromatography (GPC), and atomic force microscopy (AFM) were utilized to analyze this evolutionary process. The results indicated that the chemical components and microstructural properties of the SBR-modified asphalt underwent significant changes during the aging process under the combined effects of intense UV radiation and large temperature differences. The SBR-modified asphalt exhibited the same aging trend for both the chemical composition and microstructure of the matrix asphalt. However, its aging process in the SBR-modified asphalt was notably slower. This delay was primarily caused by the mesh structure of the SBR-modified asphalt, which created an initial buffer period during aging. Additionally, the degradation of SBR replenished the lost components in the asphalt colloid and inhibited the aging process. The research results indicated that the SBR-modified asphalt exhibited superior aging and cracking resistance with respect to the matrix asphalt. However, the critical cracking time for the surface cracks in the SBR-modified asphalt was earlier than that in the matrix asphalt under the combined effects. It was suggested to use the "modulus ratio" (defined as the Young's modulus ratio of the surface asphalt layer to the underlying asphalt layer) to quantitatively assess the risk of surface cracking, with a higher modulus ratio indicating a greater risk of cracking or a higher degree of cracking.
在高海拔寒冷地区,强烈的紫外线(UV)辐射常常伴随着较大的温差。因此,研究丁苯橡胶(SBR)改性沥青在强烈紫外线辐射和较大温差作用下的老化行为,对于延长高海拔寒冷地区SBR改性沥青路面的使用寿命和进行养护至关重要。本研究通过分析基质沥青和SBR改性沥青在综合作用下的化学成分、微观结构和微观力学性能,研究了SBR改性沥青的老化过程。利用衰减全反射傅里叶变换红外光谱(ATR-FTIR)、凝胶渗透色谱(GPC)和原子力显微镜(AFM)来分析这一演变过程。结果表明,在强烈紫外线辐射和较大温差的综合作用下,SBR改性沥青的化学成分和微观结构性能在老化过程中发生了显著变化。SBR改性沥青在基质沥青的化学成分和微观结构方面呈现出相同的老化趋势。然而,其在SBR改性沥青中的老化过程明显较慢。这种延迟主要是由SBR改性沥青的网状结构引起的,该结构在老化过程中创造了一个初始缓冲期。此外,SBR的降解补充了沥青胶体中损失的成分并抑制了老化过程。研究结果表明,SBR改性沥青相对于基质沥青表现出优异的抗老化和抗裂性能。然而,在综合作用下,SBR改性沥青表面裂缝的临界开裂时间比基质沥青早。建议使用“模量比”(定义为表面沥青层与下层沥青层的杨氏模量比)来定量评估表面开裂风险,模量比越高表明开裂风险越大或开裂程度越高。