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炭黑-超高分子量聚乙烯复合材料的拉伸变形与横向应变行为

Tensile Deformation and Transverse Strain Behavior of Carbon Black-UHMWPE Composites.

作者信息

Solberg Peder C, Van Citters Douglas W

机构信息

Thayer School of Engineering, Dartmouth College, Hanover, NH 03755, USA.

出版信息

Materials (Basel). 2025 May 28;18(11):2542. doi: 10.3390/ma18112542.

Abstract

Electrically conductive composites of ultra-high molecular weight polyethylene (UHMWPE) may be of interest as strain sensors for event detection in high-strain scenarios, with potential applications in ballistics or orthopedics. In this study, geometric deformations of electrically conductive composites of UHMWPE were quantified for large plastic strains via physical measurements. These measurements were compared to neat (non-composite) control materials, and to geometrical behaviors predicted under volume conservation assumptions. This study found that material geometry remained close to that predicted by volume conservation at low-to-moderate plastic strains, with differences exceeding 5% only above 100% nominal strain. Materials with higher filler loading experienced a greater increase in measured volume than neat controls, particularly at higher strains. The results suggest that this difference could be due in part to volumetric opening in the composite materials with high filler loading. Finally, necking behavior was observed and quantified in this study, presenting another effect that should be taken into account for future work characterizing the electrical behavior of these materials under large plastic deformations. The results of this study thus lay the foundation for further characterization of these electrically-conductive composites, and to determine their intrinsic electrical properties as a function of strain in particular.

摘要

超高分子量聚乙烯(UHMWPE)的导电复合材料作为高应变场景下事件检测的应变传感器可能会受到关注,在弹道学或骨科领域有潜在应用。在本研究中,通过物理测量对UHMWPE导电复合材料在大塑性应变下的几何变形进行了量化。将这些测量结果与纯(非复合)对照材料以及在体积守恒假设下预测的几何行为进行了比较。本研究发现,在低至中等塑性应变下,材料几何形状与体积守恒预测的形状接近,仅在名义应变超过100%时差异才超过5%。填料含量较高的材料测得的体积增加量比纯对照材料更大,尤其是在较高应变时。结果表明,这种差异可能部分归因于高填料含量复合材料中的体积开口。最后,本研究观察并量化了颈缩行为,这是未来在大塑性变形下表征这些材料电学行为时应考虑的另一个影响因素。因此,本研究结果为进一步表征这些导电复合材料奠定了基础,特别是确定它们作为应变函数的固有电学性质。

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